(3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Base Information

Chemical Name:(3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on
CAS No.:83020-76-2
Molecular Formula:C₁₅H₂₀O₃
Molecular Weight:248.322
Hs Code.:

Synonyms:(3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Suppliers and Price of (3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

There total 4 articles about (3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 83020-82-0
4-Hydroxy-4-[(E)-5-(1-methoxy-1-methyl-ethoxy)-3-methyl-pent-3-en-1-ynyl]-3,5,5-trimethyl-cyclohex-2-enone

: 83020-76-2
(3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Guidance literature:: With sulfuric acid; In acetone; at 0 ℃; for 0.25h;
DOI:10.1002/hlca.19820650328

Reference yield:

: 80713-62-8
5-(1-methoxy-1-methylethoxy)-3-methyl-3E-penten-1-yne

: 83020-76-2
(3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Guidance literature:: Multi-step reaction with 2 steps

1: 62.0 g / LiNH₂ / liquid ammonia; diethyl ether / 2.5 h / -40 °C

2: 3N H₂SO₄ / acetone / 0.25 h / 0 °C

With lithium amide; sulfuric acid; In diethyl ether; ammonia; acetone;
DOI:10.1002/hlca.19820650328

Reference yield:

: 80713-62-8
5-(1-methoxy-1-methylethoxy)-3-methyl-3E-penten-1-yne

: 83020-75-1
oxophorone trimethylsilylenol ether

: 83020-76-2
(3'E)-4-hydroxy-4-(5'-hydroxy-3'-methyl-3'-penten-1'-inyl)-3,5,5-trimethyl-2-cyclohexen-1-on

Guidance literature:: With n-butyllithium; sulfuric acid; Multistep reaction; 1.) THF, hexane, 0 deg C, 2 h, 2.) THF, hexane, 0 deg C, 18 h;
DOI:10.1002/hlca.19820650328