(3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

Base Information

Chemical Name:(3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene
CAS No.:299159-75-4
Molecular Formula:C₂₄H₂₅NO₂Si
Molecular Weight:387.554
Hs Code.:

Synonyms:(3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

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Chemical Property of (3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

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Technology Process of (3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

There total 4 articles about (3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₄H₂₅NO₂Si

: 299159-75-4
(3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

Guidance literature:: In toluene; at 20 ℃;
DOI:10.1021/ja000248o

Reference yield:

: 18419-53-9
vinyldiphenylchlorosilane

: 299159-75-4
(3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole / tetrahydrofuran / 1 h / 20 °C

2: DIBAH / toluene / 0.5 h / -78 °C

3: toluene / -78 - 20 °C

4: toluene / 20 °C

With 1H-imidazole; diisobutylaluminium hydride; In tetrahydrofuran; toluene; 1: silylation / 2: Reduction / 3: Condensation / 4: Cyclization;
DOI:10.1021/ja000248o

Reference yield:

: 299159-66-3
ethyl (S)-O-(diphenylvinylsilyl)lactate

: 299159-75-4
(3aR,6S,6aS)-1-Benzyl-6-methyl-4,4-diphenyl-tetrahydro-2,5-dioxa-1-aza-4-sila-pentalene

Guidance literature:: Multi-step reaction with 3 steps

1: DIBAH / toluene / 0.5 h / -78 °C

2: toluene / -78 - 20 °C

3: toluene / 20 °C

With diisobutylaluminium hydride; In toluene; 1: Reduction / 2: Condensation / 3: Cyclization;
DOI:10.1021/ja000248o