Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

Base Information

Chemical Name:Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate
CAS No.:946570-34-9
Molecular Formula:C₂₉H₄₄O₅
Molecular Weight:472.665
Hs Code.:

Synonyms:Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

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Chemical Property of Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

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Technology Process of Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

There total 7 articles about Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 5-methyl-3-(2-methylpropyl)hexanoyl chloride

: 946570-29-2
Z-5-(hydroxymethyl)-3-(3-methylbutylidene)-5-[(phenylmethoxy)methyl]-4,5-dihydrofuran-2-one

: 946570-34-9
Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

Guidance literature:: With triethylamine; dmap; In dichloromethane; at 0 - 20 ℃; for 0.166667h;
DOI:10.1021/jm0702579

Reference yield:

: 946570-24-7
Z-5-[(4-methoxyphenoxy)methyl]-3-(3-methylbutylidene)-5-[(phenylmethoxy)methyl]-4,5-dihydrofuran-2-one

: 946570-34-9
Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / ceric ammonium nitrate / acetonitrile; H₂O / 0.25 h / 0 °C

2: 43 percent / Et₃N / dimethylaminopyridine / CH₂Cl₂ / 0.17 h / 0 - 20 °C

With ammonium cerium(IV) nitrate; triethylamine; dmap; In dichloromethane; water; acetonitrile;
DOI:10.1021/jm0702579

Reference yield:

: C₂₅H₃₂O₆

: 946570-34-9
Z-{4-(3-methylbutylidene)-5-oxo-2-[(phenylmethoxy)methyl]-2-(2,3-dihydrofuryl)}methyl 5-methyl-3-(2-methylpropyl)hexanoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Et₃N; methanesulfonyl chloride / CH₂Cl₂ / 0.17 h / 20 °C

1.2: 260 mg / 1,8-diazabicyclo[5.4.0]undec-7-ene / CH₂Cl₂ / 20 °C

2.1: 100 percent / ceric ammonium nitrate / acetonitrile; H₂O / 0.25 h / 0 °C

3.1: 43 percent / Et₃N / dimethylaminopyridine / CH₂Cl₂ / 0.17 h / 0 - 20 °C

With ammonium cerium(IV) nitrate; methanesulfonyl chloride; triethylamine; dmap; In dichloromethane; water; acetonitrile;
DOI:10.1021/jm0702579