2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

Base Information

Chemical Name:2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside
CAS No.:904319-32-0
Molecular Formula:C₅₂H₅₈O₁₃Si
Molecular Weight:919.11
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

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Chemical Property of 2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

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Technology Process of 2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

There total 9 articles about 2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 904319-31-9
2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-3-O-p-methoxybenzyl-β-D-glucopyranoside

: 904319-32-0
2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 20 ℃; for 10h;
DOI:10.1016/j.carres.2006.04.019

Reference yield:

: 904319-28-4
phenyl 4,6-O-benzylidene-3-O-benzyl-2-O-chloroacetyl-1-thio-β-D-glucopyranoside

: 904319-32-0
2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 57 percent / N-iodosuccinimide; trifluoromethanesulfonic acid; 4 Angstroem molecular sieves / CH₂Cl₂ / -40 °C

2: 77 percent / NaHCO₃ / methanol; H₂O; tetrahydrofuran / 1 h / 50 °C

3: CH₂Cl₂; pyridine / 2 h / -20 - 0 °C

4: 501 mg / dimethylformamide / 2.5 h / 20 - 100 °C

5: 78 percent / DDQ / CH₂Cl₂; H₂O / 10 h / 20 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; pyridine; methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.carres.2006.04.019

Reference yield:

: 904319-27-3
2-(trimethylsilyl)ethyl 2-O-benzoyl-6-O-benzyl-3-O-p-methoxybenzyl-β-D-glucopyranoside

: 904319-32-0
2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-O-benzoyl-3-O-benzyl-β-D-mannopyranosyl-(1->4)-2-O-benzoyl-6-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 57 percent / N-iodosuccinimide; trifluoromethanesulfonic acid; 4 Angstroem molecular sieves / CH₂Cl₂ / -40 °C

2: 77 percent / NaHCO₃ / methanol; H₂O; tetrahydrofuran / 1 h / 50 °C

3: CH₂Cl₂; pyridine / 2 h / -20 - 0 °C

4: 501 mg / dimethylformamide / 2.5 h / 20 - 100 °C

5: 78 percent / DDQ / CH₂Cl₂; H₂O / 10 h / 20 °C

With N-iodo-succinimide; trifluorormethanesulfonic acid; 4 A molecular sieve; sodium hydrogencarbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; pyridine; methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/j.carres.2006.04.019