(2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

Base Information

Chemical Name:(2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide
CAS No.:375373-53-8
Molecular Formula:C₃₀H₂₇O₄P
Molecular Weight:482.516
Hs Code.:

Synonyms:(2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

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Chemical Property of (2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

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Technology Process of (2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

There total 2 articles about (2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 101111-39-1
diphenyl allylphosphonate

: 375373-53-8
(2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 56.6 percent / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / -78 °C

2: 97.4 percent / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 5 h / Heating

Grubbs catalyst first generation; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane;
DOI:10.1021/ol016491p

Reference yield:

: Lithium; (S)-1-trityloxy-but-3-en-2-olate

: 375373-53-8
(2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 56.6 percent / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / -78 °C

2: 97.4 percent / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 5 h / Heating

Grubbs catalyst first generation; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane;
DOI:10.1021/ol016491p

Reference yield: 69.6%

: 375373-53-8
(2S,6S)-2-Phenoxy-6-trityloxymethyl-3,6-dihydro-[1,2]oxaphosphinine 2-oxide

: 375373-54-9
(2S,4R,5S,6R)-2-Oxo-2-phenoxy-6-trityloxymethyl-2λ⁵-[1,2]oxaphosphinane-4,5-diol

Guidance literature:: With osmium(VIII) oxide; N-methyl-2-indolinone; citric acid; In acetone; tert-butyl alcohol; for 24h;
DOI:10.1021/ol016491p