9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl

Base Information

Chemical Name:9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl
CAS No.:37167-64-9
Molecular Formula:C₂₆H₁₆Cl₂
Molecular Weight:399.319
Hs Code.:
DSSTox Substance ID:DTXSID501299194
Nikkaji Number:J2.495.069G

Synonyms:9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl;DTXSID501299194;9,9'-Dichloro-9,9'-bi-9H-fluorene;9,9'-Dichloro-9,9'-bi[9H-fluorene];37167-64-9

Suppliers and Price of 9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl

Chemical Property:

XLogP3:6.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:398.0629059
Heavy Atom Count:28
Complexity:503

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C2C(=C1)C3=CC=CC=C3C2(C4(C5=CC=CC=C5C6=CC=CC=C64)Cl)Cl

Technology Process of 9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl

There total 1 articles about 9,9'-Dichloro-9H,9'H-[9,9']bifluorenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 58120-06-2
N-Chlor-9-fluorenonimin

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

: 486-25-9,952573-42-1
9-fluorenone

: 37167-64-9
9,9'-dichloro-9,9'-bifluorenyl

Guidance literature:: DOI:10.1021/ja01194a515

Reference yield: 58.0%

: 15318-33-9,16353-77-8,13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

: 37167-64-9
9,9'-dichloro-9,9'-bifluorenyl

: 16969-79-2,24322-80-3
Rh(CO)(P(C₆H₅)3)2Cl₃

: 746-47-4
tetrabenzo[5.5]fulvalene

Guidance literature:: In tetrahydrofuran; a suspn. of Rh complex and 9,9'-dichlorobisfluorenyl in THF in 1:1 moleratio was heated at 50°C for 4.5 h under N2; solvent was removed, residue extd. with hexane to give bisfluorenylidene, residue was chromd. (Al2O3, CHCl3 eluent) to give RhCl3(CO)(PPh3)2;
DOI:10.1016/S0022-328X(00)89039-7

Reference yield: 48.0%

: (Rh(CO)(P(C₆H₅)3)2)2*2C₄H₈O

: 37167-64-9
9,9'-dichloro-9,9'-bifluorenyl

: 15318-33-9,16353-77-8,13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

: 16969-79-2,24322-80-3
Rh(CO)(P(C₆H₅)3)2Cl₃

: 746-47-4
tetrabenzo[5.5]fulvalene

Guidance literature:: In tetrahydrofuran; a suspn. of Rh complex and 9,9'-dichlorobisfluorenyl in THF in 1:1 moleratio was heated at 50°C for 8 h under N2; solvent was removed, residue extd. with hexane to give bisfluorenylidene, residue was extd. with benzene to give RhCl(CO)(PPh3)2, the benzene-insoluble residue was chromd. (Al2O3, CHCl3 eluent) to give RhCl3(CO)(PPh3)2;
DOI:10.1016/S0022-328X(00)89039-7