{(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2

Base Information

• Chemical Name: {(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2
• CAS No.: 111495-67-1
• Molecular Formula: 2C₂₄H₂₀B*C₆₉H₅₈As₂ClIr₂O₅P₄Rh
• Molecular Weight: 2402.22
• Mol file: 111495-67-1.mol

Synonyms:{(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2

Chemical Property of {(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2

There total 1 articles about {(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

{(iridium)2rhodium(μ-carbonyl)2(carbonyl)2(μ-chloro)chloro(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}tetraphenylborate (111765-82-3) + sodium tetraphenyl borate (143-66-8) → {(iridium)2rhodium(μ-carbonyl)2(carbonyl)3(μ-chloro)(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}{tetraphenylborate}2 (111495-67-1)

Guidance literature:

With CO; In methanol; dichloromethane; Addn. of NaB(C6H5)4-soln. in MeOH to complex in CH2Cl2, resulting red. soln. is purged with CO for 3 h.; Addn. of MeOH pptd. bright red needles, washing (MeOH, diethyl ether), elem. anal.;

upstream raw materials:

{(iridium)2rhodium(μ-carbonyl)2(carbonyl)2(μ-chloro)chloro(μ-bis((diphenylphosphino)-methyl)phenylarsine)2}tetraphenylborate

sodium tetraphenyl borate