2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

Base Information

Chemical Name:2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene
CAS No.:349489-77-6
Molecular Formula:C₂₆H₃₅N₃O₆S₂
Molecular Weight:549.712
Hs Code.:

Synonyms:2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

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Chemical Property of 2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

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Technology Process of 2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

There total 4 articles about 2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 98-59-9
p-toluenesulfonyl chloride

: 349489-76-5
2,2-bis(hydroxymethyl)-1H,4H,7H-pentahydro-3a,6a,9a-triazaphenalenium

: 349489-77-6
2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

Guidance literature:: p-toluenesulfonyl chloride; 2,2-bis(hydroxymethyl)-1H,4H,7H-pentahydro-3a,6a,9a-triazaphenalenium; With pyridine; dmap; In dichloromethane; at 0 ℃; for 24h;

With sodium tetrahydroborate; In tetrahydrofuran; at 20 ℃; for 48h;
DOI:10.1016/S0040-4039(01)00238-6

Reference yield:

: 2209-89-4
(2-phenyl-1,3-dioxane-5,5-diyl)di(methylene) bis(4-methylbenzenesulfonate)

: 349489-77-6
2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 99.1 percent / H₂ / Pd/C / ethanol / 15 h / 20 °C / 3800 Torr

2.1: 1,2-dimethoxy-ethane / 24 h / 40 °C

3.1: pyridine; DMAP / CH₂Cl₂ / 24 h / 0 °C

3.2: 33 percent / NaBH₄ / tetrahydrofuran / 48 h / 20 °C

With pyridine; dmap; hydrogen; palladium on activated charcoal; In 1,2-dimethoxyethane; ethanol; dichloromethane;
DOI:10.1016/S0040-4039(01)00238-6

Reference yield:

: 2425-41-4
5,5-dihydroxymethyl-2-phenyl-1,3-dioxane

: 349489-77-6
2,2-bis(toluene-4-sulfonyloxymethyl)-1H,4H,7H-hexahydro-3a,6a,9a-triazaphenalene

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine / 20 °C

2.1: 99.1 percent / H₂ / Pd/C / ethanol / 15 h / 20 °C / 3800 Torr

3.1: 1,2-dimethoxy-ethane / 24 h / 40 °C

4.1: pyridine; DMAP / CH₂Cl₂ / 24 h / 0 °C

4.2: 33 percent / NaBH₄ / tetrahydrofuran / 48 h / 20 °C

With pyridine; dmap; hydrogen; palladium on activated charcoal; In 1,2-dimethoxyethane; ethanol; dichloromethane;
DOI:10.1016/S0040-4039(01)00238-6