C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

Base Information

Chemical Name:C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine
CAS No.:361521-95-1
Molecular Formula:C₃₅H₅₃NO₂Si₂
Molecular Weight:575.982
Hs Code.:

C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

Synonyms:C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

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Chemical Property of C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

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Technology Process of C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

There total 8 articles about C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 361521-94-0
(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalene-4a-carbonitrile

: 361521-95-1
C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

Guidance literature:: With diisobutylaluminium hydride; In toluene; at 0 - 20 ℃;
DOI:10.1016/S0040-4039(01)00840-1

Reference yield:

: 361521-89-3
(3R,4R)-3-(1,3-dioxolan-2-yl)-3,4-dimethyl-2-oxo-cyclohexanecarbonitrile

: 361521-95-1
C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

Guidance literature:: Multi-step reaction with 7 steps

1: pyrrolidine / toluene / Heating

2: 93 percent / H₂ / Pd/C / methanol

3: NaBH₄ / propan-2-ol / 0 °C

4: PPTS / acetone; H₂O / Heating

5: 98 percent / Et₃N / tetrahydrofuran / 20 °C

6: 92 percent / BuLi / tetrahydrofuran / -20 - 0 °C

7: 95 percent / DIBAH / toluene / 0 - 20 °C

With pyrrolidine; sodium tetrahydroborate; n-butyllithium; hydrogen; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; water; isopropyl alcohol; acetone; toluene; 6: Wittig reaction;
DOI:10.1016/S0040-4039(01)00840-1

Reference yield:

: 5-(tert-butyl-diphenyl-silanyloxy)-pent-3-en-2-one

: 361521-95-1
C-[(1S,2R,4aS,5S,7R,8aR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-1,2-dimethyl-7-trimethylsilanyloxy-1-vinyl-octahydro-naphthalen-4a-yl]-methyleneamine

Guidance literature:: Multi-step reaction with 7 steps

1: pyrrolidine / toluene / Heating

2: 93 percent / H₂ / Pd/C / methanol

3: NaBH₄ / propan-2-ol / 0 °C

4: PPTS / acetone; H₂O / Heating

5: 98 percent / Et₃N / tetrahydrofuran / 20 °C

6: 92 percent / BuLi / tetrahydrofuran / -20 - 0 °C

7: 95 percent / DIBAH / toluene / 0 - 20 °C

With pyrrolidine; sodium tetrahydroborate; n-butyllithium; hydrogen; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; triethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; water; isopropyl alcohol; acetone; toluene; 6: Wittig reaction;
DOI:10.1016/S0040-4039(01)00840-1