methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside

Base Information

• Chemical Name: methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside
• CAS No.: 99806-77-6
• Molecular Formula: C₂₀H₂₆FNO₄
• Molecular Weight: 363.429
• Mol file: 99806-77-6.mol

Synonyms:methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside

Chemical Property of methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside

There total 1 articles about methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Methanesulfonic acid (4aR,6S,7S,8R,8aS)-8-diallylamino-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester (98870-70-3) → methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside (99806-77-6)

Guidance literature:

With triethylamine tris(hydrogen fluoride); at 70 ℃; for 2h; Yield given;

DOI:10.1016/S0040-4020(01)96369-0

Reference yield: 95.0%

methyl-4-6-O-benzylidene-2,3-didesoxy-3-diallylamino-2-fluoro-α-D-altropyranoside (99806-77-6) → methyl-3-amino-4,6-O-benzylidene-2,3-didesoxy-2-fluoro-α-D-altropyranoside (101400-25-3)

Guidance literature:

With sodium hydrogencarbonate; palladium on activated charcoal; In water; xylene; for 10h; Heating;

DOI:10.1016/S0040-4020(01)96369-0

upstream raw materials:

Methanesulfonic acid (4aR,6S,7S,8R,8aS)-8-diallylamino-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester

Downstream raw materials:

methyl-3-amino-4,6-O-benzylidene-2,3-didesoxy-2-fluoro-α-D-altropyranoside