N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Base Information

Chemical Name:N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene
CAS No.:315716-46-2
Molecular Formula:C₄₂H₇₅N₃Si₂
Molecular Weight:678.249
Hs Code.:

Synonyms:N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Suppliers and Price of N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

There total 3 articles about N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 89343-06-6
tris-iso-propylsilyl acetylene

: N,N-Diethyl-N'-(4-decyl-2,6-diiodophenyl)triazene

: 315716-46-2
N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Guidance literature:: With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; at 60 ℃;
DOI:10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y

Reference yield:

: 37529-30-9
4-n-decylaniline

: 315716-46-2
N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 81 percent / CaCO₃; (BnEt₃N)ICl₂ / methanol; CH₂Cl₂ / 50 °C

2.1: aq. HCl; NaNO₂ / diethyl ether; tetrahydrofuran; acetonitrile / 0.5 h / -5 - 0 °C

2.2: 89 percent / aq. K₂CO₃ / diethyl ether; tetrahydrofuran; acetonitrile / 0.5 h

3.1: 96 percent / CuI; NEt₃ / [PdCl₂(PPh₃)2] / 60 °C

With hydrogenchloride; copper(l) iodide; triethylamine; calcium carbonate; benzyl triethylammonium dichloroiodate; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; acetonitrile; 1.1: Iodination / 2.1: Diazotization / 2.2: Addition / 3.1: Cross-coupling reaction;
DOI:10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y

Reference yield:

: 315716-43-9
4-decyl-2,6-diiodoaniline

: 315716-46-2
N,N-Diethyl-N'-[2,6-bis{(triisopropylsilyl)ethynyl}-4-decylphenyl]triazene

Guidance literature:: Multi-step reaction with 2 steps

1.1: aq. HCl; NaNO₂ / diethyl ether; tetrahydrofuran; acetonitrile / 0.5 h / -5 - 0 °C

1.2: 89 percent / aq. K₂CO₃ / diethyl ether; tetrahydrofuran; acetonitrile / 0.5 h

2.1: 96 percent / CuI; NEt₃ / [PdCl₂(PPh₃)2] / 60 °C

With hydrogenchloride; copper(l) iodide; triethylamine; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; diethyl ether; acetonitrile; 1.1: Diazotization / 1.2: Addition / 2.1: Cross-coupling reaction;
DOI:10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y