(BV)Cu

Base Information

• Chemical Name: (BV)Cu
• CAS No.: 639512-33-7
• Molecular Formula: C₆₀H₅₂CuN₄O₂
• Molecular Weight: 924.644
• Mol file: 639512-33-7.mol

Synonyms:(BV)Cu

Chemical Property of (BV)Cu

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (BV)Cu

There total 3 articles about (BV)Cu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(5,10,15,20-tetraphenyl-2:3,7:8,12:13,17:18-butanoporphyrinato)copper(II) (156220-28-9) + oxygen (80937-33-3) → (BV)Cu (639512-33-7)

Guidance literature:

With m-chloroperoxobenzoic acid; In pyridine; m-chloroperoxobenzoic acid added to a soln. of Cu complex, reacted for 30 min; evapd. (vac.), dissolved in CH2Cl2, washed (aq. satd. NaHCO3), chromd. (alumina, CH2Cl2/petroleum ether), recrystd. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1021/ic050841c

Reference yield: 80.0%

benzoylbiliverdin + copper diacetate (142-71-2) → Cu(II) benzoylbiliverdin (639512-33-7)

Guidance literature:

In toluene; (Ar), in refluxing toluene;

DOI:10.1039/b306586c

Reference yield:

tetra-β,β'-tetramethylenetetraphenylporphyrin + oxygen (80937-33-3) + copper diacetate (142-71-2) → (BV)Cu (639512-33-7)

Guidance literature:

With NaNO₂; TFA; In toluene; (C6H5)4C36H34N4 dissolved in TFA, NaNO2 added under air at room temp., poured into H2O, extd. (CH2Cl2), the org. layers washed (aq. NaHCO3, H2O), dried (Na2SO4), evapd., chromd. (alumina), dissolved in toluene, Cu salt added, refluxed for 8 h; cooled to room temp., evapd. (vac.), purified on an alumina plug, chromd. (alumina, CH2Cl2/petroleum ether), recrystd. (CH2Cl2/MeOH);

DOI:10.1021/ic050841c

upstream raw materials:

(5,10,15,20-tetraphenyl-2:3,7:8,12:13,17:18-butanoporphyrinato)copper(II)

oxygen

copper diacetate