1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

Base Information

Chemical Name:1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene
CAS No.:1416169-15-7
Molecular Formula:C₂₉H₂₉BrNPS₂
Molecular Weight:566.566
Hs Code.:

Synonyms:1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

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Chemical Property of 1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

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Technology Process of 1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

There total 2 articles about 1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1426533-37-0
2-azido-5-bromo-1-[bis(ethylthio)methyl]benzene

: 603-35-0
triphenylphosphine

: 1416169-15-7
1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

Guidance literature:: In diethyl ether; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1039/c2ob27010b

Reference yield:

: 1001621-59-5
2-azido-5-bromobenzaldehyde

: 1416169-15-7
1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

Guidance literature:: Multi-step reaction with 2 steps

1: chloro-trimethyl-silane / chloroform / 1.17 h / 20 °C

2: diethyl ether / 16 h / 20 °C / Inert atmosphere

With chloro-trimethyl-silane; In diethyl ether; chloroform; 2: |Staudinger Azide Reduction;
DOI:10.1039/c2ob27010b

Reference yield: 72.0%

: 1416169-15-7
1-[bis(ethylthio)methyl]-5-bromo-2-triphenylphosphoranylidene-aminobenzene

: 3156-07-8
methyl phenyl ketene

: trans-2,4-bis(ethylthio)-6-bromo-3-methyl-3-phenyl-3,4-dihydroquinoline

: cis-2,4-bis(ethylthio)-6-bromo-3-methyl-3-phenyl-3,4-dihydroquinoline

Guidance literature:: In dichloromethane; at 20 ℃; for 1h; Overall yield = 99 %; diastereoselective reaction; Inert atmosphere;
DOI:10.1039/c2ob27010b