3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

Base Information

Chemical Name:3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one
CAS No.:101814-80-6
Molecular Formula:C₁₄H₁₈ClNOSSi
Molecular Weight:311.908
Hs Code.:

Synonyms:3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

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Chemical Property of 3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

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Technology Process of 3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

There total 6 articles about 3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 101766-13-6
3-[1-(4-Chloro-phenylsulfanyl)-1-trimethylsilanyl-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

: 101814-80-6
3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

Guidance literature:: With tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran;
DOI:10.1016/S0040-4039(01)80837-6

Reference yield:

: 105550-54-7
1-Buta-1,2-dienylsulfanyl-4-chloro-benzene

: 101814-80-6
3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) n-BuLi

2: 1.) n-BuLi

3: 2.) Na₂SO₃, K₂HPO₄ / 1.) ether, -23 to 0 deg C 2.) H₂O, 1 h, room temp.

4: 80 percent / (n-Bu)4N⁽¹⁺⁾*F^(1-), AcOH / tetrahydrofuran

With dipotassium hydrogenphosphate; n-butyllithium; tetrabutyl ammonium fluoride; acetic acid; sodium sulfite; In tetrahydrofuran;
DOI:10.1016/S0040-4039(01)80837-6

Reference yield:

: 1-(Buta-1,2-diene-1-sulfinyl)-4-chloro-benzene

: 101814-80-6
3-[1-(4-Chloro-phenylsulfanyl)-meth-(Z)-ylidene]-4-methyl-4-trimethylsilanyl-azetidin-2-one

Guidance literature:: Multi-step reaction with 5 steps

1: TFAA, NaI, Et₃N

2: 1.) n-BuLi

3: 1.) n-BuLi

4: 2.) Na₂SO₃, K₂HPO₄ / 1.) ether, -23 to 0 deg C 2.) H₂O, 1 h, room temp.

5: 80 percent / (n-Bu)4N⁽¹⁺⁾*F^(1-), AcOH / tetrahydrofuran

With dipotassium hydrogenphosphate; n-butyllithium; tetrabutyl ammonium fluoride; acetic acid; triethylamine; trifluoroacetic anhydride; sodium iodide; sodium sulfite; In tetrahydrofuran;
DOI:10.1016/S0040-4039(01)80837-6