(Z)-11-Hexadecen-1-ol

Base Information

• Chemical Name: (Z)-11-Hexadecen-1-ol
• CAS No.: 56683-54-6
• Molecular Formula: C16H32 O
• Molecular Weight: 240.429
• Hs Code.: 2905290000
• European Community (EC) Number: 260-337-6
• UNII: RYZ05BI8ZT
• DSSTox Substance ID: DTXSID0041191
• Nikkaji Number: J721H
• Wikidata: Q27288347
• Metabolomics Workbench ID: 3149
• Mol file: 56683-54-6.mol

Synonyms:(Z)-Hexadec-11-en-1-ol;56683-54-6;Virelure;(Z)-11-Hexadecen-1-ol;(Z)-11-HEXADECENOL;11-Hexadecen-1-ol, (Z)-;11Z-hexadecen-1-ol;cis-11-Hexadecen-1-ol;Z-11-hexadecen-1-ol;EINECS 260-337-6;hexadecan-11Z-en-1-ol;UNII-RYZ05BI8ZT;RYZ05BI8ZT;AI3-35169;11-Hexadecen-1-ol, (11Z)-;(11Z)-11-Hexadecen-1-ol;11-Hexadecenol, (Z)-;SCHEMBL557030;DTXSID0041191;(11Z)-hexadec-11-en-1-ol;CHEBI:179362;LMFA05000056;MFCD00010504;AKOS015839808;LS-74872;Q27288347;(Z)-11-Hexadecen-1-ol 100 microg/mL in Acetonitrile

Chemical Property of (Z)-11-Hexadecen-1-ol

Chemical Property:

• Vapor Pressure: 5.97E-05mmHg at 25°C
• Refractive Index: 1.4608 (20℃)
• Boiling Point: 309°C at 760 mmHg
• PKA: 15.20±0.10(Predicted)
• Flash Point: 134.9°C
• PSA: 20.23000
• Density: 0.847±0.06 g/cm3 (20 ºC 760 Torr)
• LogP: 5.23600
• Storage Temp.: 2-8°C
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 13
• Exact Mass: 240.245315640
• Heavy Atom Count: 17
• Complexity: 152

Purity/Quality:

99%min ^*data from raw suppliers

(Z)-Hexadec-11-en-1-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Low toxicity by ingestion.
• Hazard Codes: Low toxicity by ingestion.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC=CCCCCCCCCCCO
• Isomeric SMILES: CCCC/C=C\CCCCCCCCCCO
• Uses: (Z)-Hexadec-11-en-1-ol is a pheromone antagonist that regulates optimal mating time in moth Helicoverpa armigera.

Technology Process of (Z)-11-Hexadecen-1-ol

There total 89 articles about (Z)-11-Hexadecen-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(Z)-11-hexadecen-1-yl acetate (34010-21-4) → (Z)-11-hexadecen-1-ol (56683-54-6)

Guidance literature:

With sodium hydroxide; In ethanol; for 1h; Heating;

DOI:10.1021/jo00374a004

Reference yield: 96.0%

(11Z)-hexadec-11-enoic acid (2416-20-8,2271-34-3) → (Z)-11-hexadecen-1-ol (56683-54-6)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 5h;

Reference yield: 92.0%

(Z)-2-(hexadec-11-en-1-yloxy)tetrahydro-2H-pyran (99159-89-4) → (Z)-11-hexadecen-1-ol (56683-54-6)

Guidance literature:

With pyridinium p-toluenesulfonate; In ethanol; at 80 ℃;

DOI:10.5012/bkcs.2011.32.8.3120

upstream raw materials:

(11Z)-hexadeca-1,11-diene

pentanal

(11?hydroxyundecyl)triphenylphosphonium bromide

(Z)-11-hexadecenal

Downstream raw materials:

(Z)-11-hexadecenal

(Z)-11-hexadecen-1-yl acetate

11-hexadecyn-1-ol

C₂₂H₃₆S

Refernces

• 1、 Quero, Carmen,Rosell, Gloria,Jimenez, Oscar,Rodriguez, Sergio,Bosch, M. Pilar,Guerrero, Angel. "New fluorinated derivatives as esterase inhibitors. Synthesis, hydration and crossed specificity studies". . p. 1047 - 1055. Retrieved 2003.
• 2、 -. "Method for synthesizing grassland spodoptera litura sex pheromone active ingredients". Paragraph 0041-0043. . Retrieved 2020/07/02.
• 3、 -. "A moth pheromone pickles preparation method (by machine translation)". Paragraph 0024. . Retrieved 2019/05/15.