Technology Process of [(((C6F5)NCH2CH2)2NCH2CH2CH2N(C6F5))ReCl]
There total 1 articles about [(((C6F5)NCH2CH2)2NCH2CH2CH2N(C6F5))ReCl] which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
TaCH(CPhMe2)Cl3(THF)2;
In
toluene;
(N2); standard Schlenk technique; soln. of Ta complex (2.1 equiv.) in toluene was slowly added by cannula to suspn. of Re complex in toluene at -20°C; mixt. was stirred at room temp. for 2 h; concd. (vac.); stored at -20°C; filtered; washed (cold toluene); dried (vac.); elem. anal.;
DOI:10.1021/ic025572u
- Guidance literature:
-
With
Na amalgam;
In
tetrahydrofuran;
byproducts: NaCl, Hg; (N2); standard Schlenk technique; precooled THF (-20°C) was addedto mixt. of Re complex and Na amalgam; mixt. was stirred for 1 h; mixt. was warmed to room temp. and stirred for 1 h; filtered over Celite; solvent removed (vac.); residue extd. (toluene); filtered; concd.; cooled to -25°C; elem. anal.;
DOI:10.1021/ic025572u
![[(((C<sub>6</sub>F<sub>5</sub>)NCH<sub>2</sub>CH<sub>2</sub>)2NCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>NH(C<sub>6</sub>F<sub>5</sub>))Re(O)Cl]](/Databaselist/images/loading.webp)
