benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Base Information

Chemical Name:benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate
CAS No.:1454882-19-9
Molecular Formula:C₂₃H₃₁O₃P
Molecular Weight:386.471
Hs Code.:

Synonyms:benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Suppliers and Price of benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

There total 3 articles about benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 533-58-4
2-Iodophenol

: R_p-(-)-menthyl benzylphosphinate

: 1454882-19-9
benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Guidance literature:: With copper(l) iodide; caesium carbonate; In toluene; at 80 ℃; for 14h; stereospecific reaction; Inert atmosphere;
DOI:10.1002/adsc.201300913

Reference yield:

: 6921-34-2
benzylmagnesium chloride

: 1454882-19-9
benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Guidance literature:: Multi-step reaction with 2 steps

1.1: pyridine / diethyl ether / 0 - 20 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: copper(l) iodide; caesium carbonate / toluene / 14 h / 80 °C / Inert atmosphere

With pyridine; copper(l) iodide; caesium carbonate; In diethyl ether; toluene;
DOI:10.1002/adsc.201300913

Reference yield:

: 95456-31-8
(1R,2S,5R)-(-)-menthyl phosphorodichloridite

: 1454882-19-9
benzyl 2-hydroxyphenyl-(-)-menthyl phosphinate

Guidance literature:: Multi-step reaction with 2 steps

1.1: pyridine / diethyl ether / 0 - 20 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: copper(l) iodide; caesium carbonate / toluene / 14 h / 80 °C / Inert atmosphere

With pyridine; copper(l) iodide; caesium carbonate; In diethyl ether; toluene;
DOI:10.1002/adsc.201300913