menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate

Base Information

• Chemical Name: menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate
• CAS No.: 1173280-51-7
• Molecular Formula: C₃₅H₃₄F₆O₂
• Molecular Weight: 600.644
• Mol file: 1173280-51-7.mol

Synonyms:menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate

Chemical Property of menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate

There total 2 articles about menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 4-formylbenzoate (1247110-38-8) + 4-[2-(3,5-di-(trifluoromethyl)-phenyl)-(E)-ethenyl]-benzyl(triphenyl)phosphonium bromide (1173280-63-1) → menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(Z)-ethenyl]benzoate + menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate (1173280-51-7)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/jo900785k

Reference yield:

menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(Z)-ethenyl]benzoate → menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate (1173280-51-7)

Guidance literature:

With iodine; In toluene; Reflux; Inert atmosphere;

DOI:10.1021/jo900785k

Reference yield: 41.0%

menthyl 4-[2-[4-(2-(3,5-bis(trifluoromethyl)phenyl)-(E)-ethenyl)phenyl]-(E)-ethenyl]benzoate (1173280-51-7) → 3-(menthyloxycarbonyl)-6-[2-(3,5-difluorophenyl)ethenyl]phenanthrene

Guidance literature:

With iodine; methyloxirane; In benzene; at 20 ℃; UV-irradiation; Inert atmosphere;

DOI:10.1021/jo900785k

upstream raw materials:

(1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 4-formylbenzoate

4-[2-(3,5-di-(trifluoromethyl)-phenyl)-(E)-ethenyl]-benzyl(triphenyl)phosphonium bromide