5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin

Base Information

• Chemical Name: 5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin
• CAS No.: 1370037-29-8
• Molecular Formula: C₆₂H₅₈N₅O₁₀
• Molecular Weight: 1033.17
• Mol file: 1370037-29-8.mol

Synonyms:5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin

Chemical Property of 5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin

There total 1 articles about 5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 8.7%

5-(4′-carboethoxymethyleneoxyphenyl)dipyrromethane (847375-27-3) + 5-formyl-1,1,3,3-tetramethylisoindolin-2-yloxyl (276885-27-9) → 5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin (1370037-29-8) + 5,15-bis(4''-carboethoxymethylene-oxy-phenyl)-10,20-bis(1',1',3',3'-tetramethyl-isoindolin-2'-yloxyl-5'-yl)porphyrin (1370037-30-1)

Guidance literature:

5-(4′-carboethoxymethyleneoxyphenyl)dipyrromethane; 5-formyl-1,1,3,3-tetramethylisoindolin-2-yloxyl; With boron trifluoride diethyl etherate; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere; Darkness;

With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; for 1h; Inert atmosphere;

DOI:10.1142/S1088424611003203

Reference yield: 90.0%

5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin (1370037-29-8) + manganese(II) acetate (638-38-0,993-02-2,2180-18-9,15411-95-7,22981-23-3,27004-39-3) → 5,10,15-tris(4''-carboethoxymethyleneoxyphenyl)-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)porphyrinato manganese(III) acetate

Guidance literature:

In methanol; for 5h; Reflux;

DOI:10.1142/S1088424611003203

Reference yield: 69.0%

5,10,15-tris[4''-carboethoxymethyleneoxyphenyl-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)]porphyrin (1370037-29-8) → 5,10,15-tris(4''-carboxymethyleneoxyphenyl)-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)-porphyrin (1370037-34-5)

Guidance literature:

With sodium hydroxide; In methanol; at 20 - 50 ℃; for 7h; pH=10; Inert atmosphere;

DOI:10.1142/S1088424611003203

upstream raw materials:

5-(4′-carboethoxymethyleneoxyphenyl)dipyrromethane

5-formyl-1,1,3,3-tetramethylisoindolin-2-yloxyl

Downstream raw materials:

5,10,15-tris(4''-carboxymethyleneoxyphenyl)-20-(1',1',3',3'-tetramethylisoindolin-2'-yloxyl-5'-yl)-porphyrin