5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole

Base Information

• Chemical Name: 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole
• CAS No.: 1613810-50-6
• Molecular Formula: C₄₄H₄₈N₂O₂
• Molecular Weight: 636.877
• Mol file: 1613810-50-6.mol

Synonyms:5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole

Chemical Property of 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole

There total 4 articles about 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole + 1-bromo-hexane (111-25-1) → 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole (1613810-50-6)

Guidance literature:

6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole; With potassium tert-butylate; In dimethyl sulfoxide; at 20 ℃; Inert atmosphere;

1-bromo-hexane; In dimethyl sulfoxide; at 20 ℃; for 1h;

DOI:10.24820/ark.5550190.p010.557

Reference yield:

5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,6,11,12-tetrahydroindolo[3,2-b]carbazole (1613810-44-8) → 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole (1613810-50-6)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; at 10 - 20 ℃; for 2h; Reagent/catalyst; Solvent; Temperature;

DOI:10.1016/j.tet.2014.04.093

Reference yield:

indole (120-72-9) → 5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole (1613810-50-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: tetra-(n-butyl)ammonium iodide; tetrafluoroboric acid / water; acetonitrile / 3 h / 15 - 20 °C

2.1: sodium hydroxide / N,N-dimethyl-formamide / 0.5 h / 20 °C / Inert atmosphere

2.2: 15 h / Inert atmosphere

3.1: pyridinium chlorochromate / dichloromethane / 2 h / 10 - 20 °C

With tetrafluoroboric acid; tetra-(n-butyl)ammonium iodide; pyridinium chlorochromate; sodium hydroxide; In dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1016/j.tet.2014.04.093

upstream raw materials:

indole

5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,6,11,12-tetrahydroindolo[3,2-b]carbazole

1-bromo-hexane

Downstream raw materials:

5,11-dihexyl-6,12-bis(4-methoxyphenyl)-5,11-dihydroindolo[3,2-b]carbazole-2,8-dicarbaldehyde