(2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

Base Information

Chemical Name:(2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one
CAS No.:108149-96-8
Molecular Formula:C₃₃H₄₇NO₃
Molecular Weight:505.741
Hs Code.:

Synonyms:(2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

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Chemical Property of (2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

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Technology Process of (2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

There total 11 articles about (2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 108149-95-7
(4S,1'S)-3-benzyl-4-<2-acethoxy-1-(benzyloxy)-3-(phenylsulfonyl)hexadecyl>-1,3-oxazolidyn-2-one

: 108149-96-8
(2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

Guidance literature:: With sodium amalgam; In methanol; ethyl acetate; at 0 ℃; for 6h;
DOI:10.1021/jo00389a035

Reference yield:

: 112-71-0
1-Bromotetradecane

: 108149-96-8
(2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: 90 percent / triethylamine, tetrabuthylammonium iodide / tetrahydrofuran / 6 h

2: 92 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h

3: 1.) n-butyllithium / 1.) THF, hexane, -78 deg. C, 30 min. ; 2.) THF, hexane, -70 deg. C, 1h

4: 51 percent / sodium amalgam / methanol; ethyl acetate / 6 h / 0 °C

With sodium amalgam; n-butyllithium; tetra-(n-butyl)ammonium iodide; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; ethyl acetate;
DOI:10.1021/jo00389a035

Reference yield:

: 94763-48-1
phenyl tetradecyl thioether

: 108149-96-8
(2'E,4S,1'R)-3-benzyl-4-<1-(benzyloxy)hexadec-2-enyl>-1,3-oxazolidyn-2-one

Guidance literature:: Multi-step reaction with 3 steps

1: 92 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 1 h

2: 1.) n-butyllithium / 1.) THF, hexane, -78 deg. C, 30 min. ; 2.) THF, hexane, -70 deg. C, 1h

3: 51 percent / sodium amalgam / methanol; ethyl acetate / 6 h / 0 °C

With sodium amalgam; n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; ethyl acetate;
DOI:10.1021/jo00389a035