ZINC pelargonate

Base Information

• Chemical Name: ZINC pelargonate
• CAS No.: 7640-78-0
• Molecular Formula: C9H18 O2 . 1/2 Zn
• Molecular Weight: 379.856
• European Community (EC) Number: 231-575-8
• UNII: 6MTE8G7YLD
• Nikkaji Number: J307.898A
• Wikidata: Q27265169
• Mol file: 7640-78-0.mol

Synonyms:ZINC PELARGONATE;Zinc nonan-1-oate;Zinc nonanoate;Nonanoic acid, zinc salt;UNII-6MTE8G7YLD;6MTE8G7YLD;7640-78-0;EINECS 231-575-8;NSC-65481;Bisnonanoic acid zinc salt;SCHEMBL6902496;C9H18O2.1/2Zn;NSC 65481;Q27265169

Chemical Property of ZINC pelargonate

Chemical Property:

• Vapor Pressure: 0.00867mmHg at 25°C
• Melting Point: 12.4oC
• Boiling Point: 254.9°C at 760 mmHg
• Flash Point: 114.9°C
• PSA: 37.30000
• LogP: 2.81910
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 12
• Exact Mass: 378.174851
• Heavy Atom Count: 23
• Complexity: 94.2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC(=O)[O-].CCCCCCCCC(=O)[O-].[Zn+2]

Technology Process of ZINC pelargonate

There total 3 articles about ZINC pelargonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

nonanoic acid (112-05-0) + zinc(II) oxide → zinc(II) nonanoate (7640-78-0)

Guidance literature:

In ethanol; prepn. by refluxing ZnO with excess of carboxylic acid in EtOH for about2 h; cooled; ppt. filtered off; washed (EtOH) repeatedly; collected; kept over silica gel in vac. desiccator; elem. anal.;

DOI:10.1016/j.saa.2006.11.007

Reference yield:

bis(dimethylcarbamodithioato-κS,κS')zinc(II) (137-30-4) + tetrabutylammonium pelargonate (34283-63-1) → {N(CH2CH2CH2CH3)4}(1+)*{Zn(S2CN(CH3)2)3}(1-) = {N(CH2CH2CH2CH3)4}{Zn(S2CN(CH3)2)3} + zinc(II) nonanoate (7640-78-0)

Guidance literature:

In acetone; reflux 2 h;

DOI:10.1039/DT9800001939

Reference yield:

bis(dimethylcarbamodithioato-κS,κS')zinc(II) (137-30-4) + N(CH3)4(1+)*OCOC8H17(1-)=[N(CH3)4][OCOC8H17] (75593-44-1) → N(CH3)4(1+)*Zn(S2CN(CH3)2)3(1-)=[N(CH3)4][Zn(S2CN(CH3)2)3] (75642-17-0) + zinc(II) nonanoate (7640-78-0)

Guidance literature:

In acetone; reflux 2 h;

DOI:10.1039/DT9800001939

upstream raw materials:

bis(dimethylcarbamodithioato-κS,κS')zinc(II)

tetrabutylammonium pelargonate

N(CH₃)4⁽¹⁺⁾*OCOC₈H₁₇^(1-)=[N(CH₃)4][OCOC₈H₁₇]

nonanoic acid

Refernces

• 1、 McCleverty, Jon A.,Spencer, Neil,Bailey, Neil A.,Shackleton, Stephen L.. "Aspects of the Inorganic Chemistry of Rubber Vulcanisation. Part 1. Reactions of Zinc Bis(dithiocarbamates) and Bis(benzothiazole-2-thiolates) with Carboxylates, and the Structure of 2(μ-OCOMe)>". . p. 1939 - 1944. Retrieved 2007/10/02.