2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane

Base Information

Chemical Name:2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane
CAS No.:1312299-22-1
Molecular Formula:C₁₉H₃₀OSi
Molecular Weight:302.532
Hs Code.:

Synonyms:2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane

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Chemical Property of 2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane

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Technology Process of 2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane

There total 2 articles about 2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1312299-17-4
4-methyl-1-[1-(dimethylphenylsilylmethyl)cyclopropyl]pentan-3-one

: 2181-42-2
trimethylsulphonium iodide

: 1312299-22-1
2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane

Guidance literature:: trimethylsulphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.0833333h;

4-methyl-1-[1-(dimethylphenylsilylmethyl)cyclopropyl]pentan-3-one; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 1.5h;
DOI:10.1021/jo200705u

Reference yield:

: 1220632-47-2
C₁₇H₂₆OSi

: 1312299-22-1
2-isopropyl-4-[1-(dimethylphenylsilylmethyl)cyclopropyl]-1,2-epoxybutane

Guidance literature:: Multi-step reaction with 2 steps

1.1: diethylzinc; trifluoroacetic acid / hexane; dichloromethane / 0.58 h / 0 °C / Inert atmosphere

1.2: 4.5 h / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / 0 °C

2.2: 1.5 h / 0 - 20 °C

With n-butyllithium; diethylzinc; trifluoroacetic acid; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo200705u