methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

Base Information

Chemical Name:methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside
CAS No.:203740-95-8
Molecular Formula:C₅₅H₅₈O₁₁
Molecular Weight:895.059
Hs Code.:

Synonyms:methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

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Technology Process of methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

There total 25 articles about methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 131531-76-5
p-methylphenyl 2,3,4,6-tetra-O-benzyl-thio-β-D-glucopyranoside

: 203740-95-8
methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

: 130144-05-7
methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

Guidance literature:: p-methylphenyl 2,3,4,6-tetra-O-benzyl-thio-β-D-glucopyranoside; With silver trifluoromethanesulfonate; dimethoxythioxaphosphoranesulfenyl bromide; In tetrachloromethane; dichloromethane; at -72 ℃; Molecular sieve; Inert atmosphere;

methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside; In tetrachloromethane; dichloromethane; at -72 - 20 ℃; Inert atmosphere; Molecular sieve;
DOI:10.1039/c0ob00380h

Reference yield:

: 38184-10-0
phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 203740-95-8
methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

: 130144-05-7
methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

Guidance literature:: With 2,4,6-tri-tert-butylpyrimidine; trifluoroethyl phenyliodonium bis((trifluoromethyl)sulfonyl)imide; In dichloromethane; at 22 ℃; for 1.5h; Overall yield = 83 %; Overall yield = 58.6 mg; Inert atmosphere;
DOI:10.1021/ol5004059

Reference yield:

: 76375-66-1
methyl 2-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside

: 744246-05-7
2-thiazolinyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside

: 203740-95-8
methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

: 130144-05-7
methyl 2-O-benzyl-3-O-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)-(1→3)-4,6-O-benzylidene-α-D-glucopyranoside

Guidance literature:: With 3 A molecular sieve; silver trifluoromethanesulfonate; In 1,2-dichloro-ethane; at 20 ℃; Title compound not separated from byproducts;
DOI:10.1002/anie.200454047