[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate

Base Information

• Chemical Name: [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate
• CAS No.: 529499-24-9
• Molecular Formula: C₄₀H₃₈N₂PRu*F₆P
• Molecular Weight: 823.763
• Mol file: 529499-24-9.mol

Synonyms:[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate

Chemical Property of [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate

There total 3 articles about [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

1,10-Phenanthroline (66-71-7) + [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate (529499-17-0) → [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate (529499-24-9)

Guidance literature:

In dichloromethane; benzene; refluxed for 1 h; evapd. to dryness, dissolved (CH2Cl2), filtered, pptd. (hexane), centrifugated, washed (hexane, diethyl ether), recrystd. (acetone/hexane);

DOI:10.1016/S0277-5387(02)01335-9

Reference yield: 73.0%

1,10-Phenanthroline (66-71-7) + [(η5-C5Me5)RuCl(PPh3)2][PF6] → [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate (529499-24-9)

Guidance literature:

[(η⁵-C₅Me₅)RuCl(PPh₃)₂][PF₆]; With silver(I) hexafluorophosphate; In dichloromethane; for 0.5h; Schlenk technique;

1,10-Phenanthroline; In dichloromethane; at 20 ℃; Schlenk technique;

DOI:10.1021/acs.inorgchem.0c01795

Reference yield:

ammonium hexafluorophosphate + 1,10-Phenanthroline (66-71-7) + pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride (92361-49-4) → [(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(1,10-phenanthroline)ruthenium(II)] hexafluorophosphate (529499-24-9)

Guidance literature:

In toluene; refluxed for 12-15 h;

DOI:10.1016/S0277-5387(02)01335-9

upstream raw materials:

1,10-Phenanthroline

pentamethylcyclopentadienyl bis(triphenylphosphine)ruthenium(II) chloride

[(η5-pentamethylcyclopentadienyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate