(E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

Base Information

Chemical Name:(E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one
CAS No.:109493-07-4
Molecular Formula:C₂₂H₃₄O₃Si
Molecular Weight:374.596
Hs Code.:

Synonyms:(E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

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Chemical Property of (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

Chemical Property:

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Technology Process of (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

There total 11 articles about (E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 109492-81-1
6-(4-methoxyphenyl)-6-methyl-9-trimethylsilylundeca-1,8-dien-5-one

: 109493-07-4
(E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

Guidance literature:: With sodium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 2h; Ambient temperature;

Reference yield:

: 104-01-8
4-Methoxyphenylacetic acid

: 109493-07-4
(E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

Guidance literature:: Multi-step reaction with 7 steps

1: HCl

2: 96.5 percent / sodamide / liquid ammonia; tetrahydrofuran / 1 h / -33 °C

3: 100 percent / 2M-aq. NaOH / ethanol / 1 h / Heating

4: 94 percent / thionyl chloride / Ambient temperature

5: 84 percent / 1.) Mg; 2.) CdCl₂ / 1.) ether, reflux, 1 h; 2.) rt., l5 min then benzene, reflux, 1 h

6: 1.) HMPA, NaH / 1.) THF, rt., 0.5 h; 2.) THF, 0 deg C, 10 min then rt.

7: 1.7 g / Na₂CO₃, m-chloroperbenzoic acid / CH₂Cl₂ / 2 h / Ambient temperature

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydroxide; thionyl chloride; sodium hydride; sodium carbonate; sodium amide; magnesium; 3-chloro-benzenecarboperoxoic acid; cadmium(II) chloride; In tetrahydrofuran; ethanol; dichloromethane; ammonia;

Reference yield:

: 36551-06-1
3-(tetrahydropyran-2-yloxy)-1-trimethylsilylprop-1-yne

: 109493-07-4
(E)-4-(4-Methoxy-phenyl)-4-methyl-1-oxiranyl-7-trimethylsilanyl-non-6-en-3-one

Guidance literature:: Multi-step reaction with 5 steps

2: 100 percent / toluene-p-sulphonic acid, K₂CO₃ / methanol / 1.5 h / Ambient temperature

3: 54 percent / pyridine, PBr₃ / diethyl ether / 1 h / Heating

4: 1.) HMPA, NaH / 1.) THF, rt., 0.5 h; 2.) THF, 0 deg C, 10 min then rt.

5: 1.7 g / Na₂CO₃, m-chloroperbenzoic acid / CH₂Cl₂ / 2 h / Ambient temperature

With pyridine; N,N,N,N,N,N-hexamethylphosphoric triamide; phosphorus tribromide; sodium hydride; sodium carbonate; potassium carbonate; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; In methanol; diethyl ether; dichloromethane;