chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I)

Base Information

• Chemical Name: chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I)
• CAS No.: 1574648-17-1
• Molecular Formula: C₂₇H₂₄ClCuN₂O₂
• Molecular Weight: 507.499
• Mol file: 1574648-17-1.mol

Synonyms:chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I)

Chemical Property of chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I)

There total 2 articles about chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(1-phenylethyl)-phenanthro[9,10-d]imidazole (1574642-37-7) → chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I) (1574648-17-1)

Guidance literature:

Multi-step reaction with 3 steps

1: 1-methyl-pyrrolidin-2-one / 72 h / 70 °C

2: Amberlyst A₂₁ charged with HCl / methanol

3: 1,4-dioxane / 18 h / Reflux; Inert atmosphere; Schlenk technique

With Amberlyst A₂₁ charged with HCl; In 1,4-dioxane; 1-methyl-pyrrolidin-2-one; methanol;

DOI:10.1002/ejic.201301499

Reference yield:

C27H25N2O2(1+)*Br(1-) → chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I) (1574648-17-1)

Guidance literature:

Multi-step reaction with 2 steps

1: Amberlyst A₂₁ charged with HCl / methanol

2: 1,4-dioxane / 18 h / Inert atmosphere; Schlenk technique; Reflux

With Amberlyst A₂₁ charged with HCl; In 1,4-dioxane; methanol;

DOI:10.1002/ejic.201301499

Reference yield: 61.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + chloro[1-ethoxycarbonylmethyl-3-(1-phenylethyl)phenanthro[9,10-d]imidazolin-2-ylidene]copper(I) (1574648-17-1) → chloro(η4-1,5-cod)[1-ethoxycarbonylmethyl-3-(1-phenylethyl)-phenanthro[9,10-d]imidazolin-2-ylidene]rhodium(I)

Guidance literature:

With calcium chloride; In chloroform; water; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201301499

upstream raw materials:

1-(1-phenylethyl)-phenanthro[9,10-d]imidazole