6,7-dimethyl-2-phenylbenzo[d]thiazole

Base Information

• Chemical Name: 6,7-dimethyl-2-phenylbenzo[d]thiazole
• CAS No.: 1620817-52-8
• Molecular Formula: C₁₅H₁₃NS
• Molecular Weight: 239.341
• Mol file: 1620817-52-8.mol

Synonyms:6,7-dimethyl-2-phenylbenzo[d]thiazole

Chemical Property of 6,7-dimethyl-2-phenylbenzo[d]thiazole

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 6,7-dimethyl-2-phenylbenzo[d]thiazole

There total 3 articles about 6,7-dimethyl-2-phenylbenzo[d]thiazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-amino-o-xylene (95-64-7) + benzylamine (100-46-9) → 5,6-dimethyl-2-phenylbenzo[d]thiazole (1422963-56-1) + 6,7-dimethyl-2-phenylbenzo[d]thiazole (1620817-52-8)

Guidance literature:

With sulfur; di-μ-hydroxo-bis[(N,N,N′,N′-tetramethylethylenediamine)copper(II)] chloride; oxygen; In dimethyl sulfoxide; at 100 ℃; for 24h; under 760.051 Torr; Overall yield = 62 percent; Overall yield = 73.6 mg;

DOI:10.1002/adsc.202000598

Reference yield:

C15H15NS (450375-91-4) → 5,6-dimethyl-2-phenylbenzo[d]thiazole (1422963-56-1) + 6,7-dimethyl-2-phenylbenzo[d]thiazole (1620817-52-8)

Guidance literature:

With p-nitrobenzene iodide; Oxone; trifluorormethanesulfonic acid; at 20 ℃; for 12h; Overall yield = 75 %; Overall yield = 65 mg; Green chemistry;

DOI:10.1021/jo501216h

Reference yield:

N-(3, 4-dimethylphenyl)benzamide (27285-18-3) → 5,6-dimethyl-2-phenylbenzo[d]thiazole (1422963-56-1) + 6,7-dimethyl-2-phenylbenzo[d]thiazole (1620817-52-8)

Guidance literature:

Multi-step reaction with 2 steps

1: Lawessons reagent

2: p-nitrobenzene iodide; trifluorormethanesulfonic acid; Oxone / 12 h / 20 °C / Green chemistry

With Lawessons reagent; p-nitrobenzene iodide; Oxone; trifluorormethanesulfonic acid;

DOI:10.1021/jo501216h

upstream raw materials:

N-(3, 4-dimethylphenyl)benzamide

C₁₅H₁₅NS

4-amino-o-xylene

benzylamine