Technology Process of 2,4-dimethyl-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid tert-butyl ester
There total 3 articles about 2,4-dimethyl-5-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)benzoic acid tert-butyl ester which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate;
In
dimethyl sulfoxide;
at 80 ℃;
for 18h;
DOI:10.1016/j.bmcl.2011.11.100
- Guidance literature:
-
Multi-step reaction with 3 steps
1: sodium periodate; sulfuric acid; iodine; acetic anhydride / acetic acid / 6 h / 105 °C
2: toluene / 2 h / 80 °C
3: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate / dimethyl sulfoxide / 18 h / 80 °C
With
sodium periodate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; sulfuric acid; iodine; potassium acetate; acetic anhydride;
In
acetic acid; dimethyl sulfoxide; toluene;
DOI:10.1016/j.bmcl.2011.11.100
- Guidance literature:
-
Multi-step reaction with 2 steps
1: toluene / 2 h / 80 °C
2: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate / dimethyl sulfoxide / 18 h / 80 °C
With
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; potassium acetate;
In
dimethyl sulfoxide; toluene;
DOI:10.1016/j.bmcl.2011.11.100
