Technology Process of C20H29ClO2
There total 5 articles about C20H29ClO2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.75 h / 0 - 20 °C / Inert atmosphere
1.2: 12 h / Inert atmosphere
2.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 4 h / 20 °C
2.2: 16 h
3.1: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / tetrahydrofuran; water; tert-butyl alcohol / 1 h / 20 °C
4.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 0 - 20 °C / Inert atmosphere
With
sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; sodium hydride; N,N-dimethyl-formamide; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; mineral oil; tert-butyl alcohol;
1.1: Williamson synthesis / 1.2: Williamson synthesis / 2.2: Suzuki coupling / 3.1: Pinnick oxidation;
DOI:10.1021/jm2001053
- Guidance literature:
-
With
oxalyl dichloride; N,N-dimethyl-formamide;
In
dichloromethane;
at 0 - 20 ℃;
Inert atmosphere;
DOI:10.1021/jm2001053
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 9-bora-bicyclo[3.3.1]nonane / tetrahydrofuran / 4 h / 20 °C
1.2: 16 h
2.1: sodium dihydrogenphosphate; sodium chlorite; 2-methyl-but-2-ene / tetrahydrofuran; water; tert-butyl alcohol / 1 h / 20 °C
3.1: oxalyl dichloride; N,N-dimethyl-formamide / dichloromethane / 0 - 20 °C / Inert atmosphere
With
sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; N,N-dimethyl-formamide; 9-bora-bicyclo[3.3.1]nonane;
In
tetrahydrofuran; dichloromethane; water; tert-butyl alcohol;
1.2: Suzuki coupling / 2.1: Pinnick oxidation;
DOI:10.1021/jm2001053