(-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

Base Information

Chemical Name:(-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde
CAS No.:1428990-20-8
Molecular Formula:C₃₁H₃₅BrO₄Si
Molecular Weight:579.606
Hs Code.:

Synonyms:(-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

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Chemical Property of (-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

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Technology Process of (-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

There total 6 articles about (-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 2973-58-2
2-bromoisovanillin

: 1428990-16-2
2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyl ethenyl carbonate

: 1428990-20-8
(-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

: tert-butyl(cyclohexa-1,5-dienylmethoxy)diphenylsilane

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); (S)-2,2'-bis[bis(m-xylyl)phosphinoxy]-3,3'-bis(2,4,6-trimethylbenzyl)-5,5',6,6'-tetramethyl-1,1'-biphenyl; In N,N-dimethyl-formamide; at 0 ℃; for 36h; Time; Reagent/catalyst; Concentration; Temperature; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/jo400355j

Reference yield:

: 1428990-16-2
2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyl ethenyl carbonate

: 1428990-20-8
(-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

: C₃₂H₃₅BrO₄

: tert-butyl(cyclohexa-1,5-dienylmethoxy)diphenylsilane

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); (S)-2,2'-bisdiphenylphosphinoxy-3,3'-bis(4-phenylbenzyl)-5,5',6,6'-tetramethyl-1,1'-biphenyl; triethylamine; In acetonitrile; at 0 ℃; for 24h; Reagent/catalyst; enantioselective reaction;
DOI:10.1021/jo400355j

Reference yield:

: 2973-58-2
2-bromoisovanillin

: 1428990-16-2
2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyl ethenyl carbonate

: 1428990-20-8
(-)-2-bromo-3-(2-((tert-butyldiphenylsiloxy)methyl)cyclohex-2-enyloxy)-4-methoxybenzaldehyde

: C₃₂H₃₅BrO₄

: tert-butyl(cyclohexa-1,5-dienylmethoxy)diphenylsilane

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); C₆₂H₅₂O₂P₂; In acetonitrile; at 0 ℃; for 24h; Solvent; Reagent/catalyst; Temperature; Time; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/jo400355j