2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene

Base Information

• Chemical Name: 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene
• CAS No.: 101472-22-4
• Molecular Formula: C₃₀H₃₄
• Molecular Weight: 394.6

Synonyms:2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene

Chemical Property of 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene

There total 1 articles about 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

1,5-bis-(4-vinyl-phenyl)-pentane (79541-69-8) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6) → 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.25,8]icosa-1(17),5,7,14(18),15,19-hexaene (101472-22-4)

Guidance literature:

With trifluorormethanesulfonic acid; In hexane; at 50 ℃; for 0.333333h;

DOI:10.1021/jo00360a034

Reference yield:

2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.25,8]icosa-1(17),5,7,14(18),15,19-hexaene (101472-22-4) → Toluene-4-sulfonic acid 1-((2S,4R)-4-methyl-tricyclo[12.2.2.25,8]icosa-1(17),5,7,14(18),15,19-hexaen-2-yl)-ethyl ester (101472-42-8)

Guidance literature:

Multi-step reaction with 3 steps

2: 86 percent / diethyl ether

3: 100 percent / pyridine / 0 - 25 °C

With pyridine; In diethyl ether;

DOI:10.1021/jo00360a034

Reference yield:

2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.25,8]icosa-1(17),5,7,14(18),15,19-hexaene (101472-22-4) → cis-1-methyl-3-((tosyloxy)methyl)<3.5>paracyclophane (101472-38-2)

Guidance literature:

Multi-step reaction with 3 steps

2: 100 percent / LiAlH₄ / diethyl ether

3: 100 percent / pyridine / 0 - 25 °C

With pyridine; lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1021/jo00360a034

upstream raw materials:

1,5-bis-(4-vinyl-phenyl)-pentane

isopropenylbenzene

Downstream raw materials:

Toluene-4-sulfonic acid 1-((2S,4R)-4-methyl-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaen-2-yl)-ethyl ester

cis-1-methyl-3-((tosyloxy)methyl)<3.5>paracyclophane

trans-1-methyl-3-((tosyloxy)methyl)<3.5>paracyclophane

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 101472-22-4 2-Methyl-4-((E)-2-phenyl-propenyl)-tricyclo[12.2.2.2^5,8]icosa-1⁽¹⁷⁾,5,7,14⁽¹⁸⁾,15,19-hexaene

Send

Send

Metric Ton KG G Pound L ML

Send

Send