CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2

Base Information

• Chemical Name: CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2
• CAS No.: 33394-10-4
• Molecular Formula: C₃₉H₃₃Cl₂IrO₂P₂
• Molecular Weight: 858.763
• Mol file: 33394-10-4.mol

Synonyms:CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2

Chemical Property of CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2

There total 5 articles about CH₃C(O)IrCl₂(CO){P(C₆H₅)3}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

trans-MeOIr(CO)(PPh3)2 (94070-38-9) → HIrCl2(CO)(PPh3)2 (17000-10-1) + CH3C(O)IrCl2(CO){P(C6H5)3}2 (33394-10-4) + acetic acid methyl ester (79-20-9)

Guidance literature:

With acetyl chloride; In benzene; soln. placed in a pressure tube fitted with a Teflon stopcock, degassed (vac.), acetyl chloride distilled onto the soln., stirred (1 h); solvent removed by vac. distillation; relation of yield to by-product yield depending on the purity of CH3COCl used and on the care of work up;

DOI:10.1021/om00105a034

Reference yield:

trans-MeOIr(CO)(PPh3)2 (94070-38-9) → CH3C(O)IrCl2(CO){P(C6H5)3}2 (33394-10-4) + acetic acid methyl ester (79-20-9)

Guidance literature:

With acetyl chloride; In benzene; The soln. of reagents in C6H6 was stirred for 1 h;; solvent was removed by vac. distillation;;

Reference yield:

trans-PhOIr(CO)(PPh3)2 (94070-40-3) → HIrCl2(CO)(PPh3)2 (17000-10-1) + CH3C(O)IrCl2(CO){P(C6H5)3}2 (33394-10-4) + Phenyl acetate (122-79-2,34474-31-2)

Guidance literature:

With acetyl chloride; In cyclohexane; soln. placed in a pressure tube fitted with a Teflon stopcock, degassed (vac.), acetyl chloride distilled onto the soln., stirred (1 h), solvent removed by vac. distillation;

DOI:10.1021/om00105a034

upstream raw materials:

trans-MeOIr(CO)(PPh₃)2

trans-PhOIr(CO)(PPh₃)2

(P(C₆H₅)3)2(CO)Ir(NC₄H₄)(C(O)CH₃)Cl

Downstream raw materials:

HIrCl₂(CO)(PPh₃)2

Refernces

• 1、 Bernard, Karen A.,Atwood, Jim D.. "Reactions of iridium(I) alkoxide complexes with acyl and alkyl sources: Carbon-oxygen bond-forming reactions". . p. 795 - 800. Retrieved 2008/10/08.
• 2、 Blake, D. M.,Vinson, A.,Dye, R.. "NEW COORDINATIVELY UNSATURATED ACYLIRIDIUM(III) COMPOUNDS INCLUDING A NEW PYRUVOYL COMPLEX. SYNTHESIS, KINETICS AND THERMOCHEMISTRY". . p. 257 - 266. Retrieved 2007/10/02.