C₁₂H₁₄OS

Base Information

• Chemical Name: C₁₂H₁₄OS
• CAS No.: 941270-73-1
• Molecular Formula: C₁₂H₁₄OS
• Molecular Weight: 206.309
• Mol file: 941270-73-1.mol

Synonyms:C₁₂H₁₄OS

Chemical Property of C₁₂H₁₄OS

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₁₂H₁₄OS

There total 1 articles about C₁₂H₁₄OS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl 2-diazopropanoate (34757-14-7) + phenyl propargyl sulfide (5651-88-7) → C12H14OS (941270-73-1)

Guidance literature:

methyl 2-diazopropanoate; phenyl propargyl sulfide; dirhodium tetraacetate; In toluene; at 60 ℃;

With lithium aluminium tetrahydride; In tetrahydrofuran; toluene; at 0 ℃; for 0.333333h; Further stages.;

DOI:10.1021/ol070205d

Reference yield: 76.0%

C12H14OS (941270-73-1) → 2-methyl-2-(phenylthio)penta-3,4-dienal (939985-43-0)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/anie.200604299

Reference yield:

C12H14OS (941270-73-1) → 3,5-dimethyl-1-phenyl-2-(phenylthio)pyrrole

Guidance literature:

Multi-step reaction with 2 steps

1: Dess-Martin reagent / CH₂Cl₂ / 20 °C

2: 48 percent / p-toluenesulfonic acid monohydrate / CH₂Cl₂ / 72 h / 20 °C

With Dess-Martin periodane; toluene-4-sulfonic acid; In dichloromethane; 1: Dess-Martin oxidation;

DOI:10.1021/ol070205d

upstream raw materials:

methyl 2-diazopropanoate

phenyl propargyl sulfide

Downstream raw materials:

2-methyl-2-(phenylthio)penta-3,4-dienal

Refernces