phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

Base Information

Chemical Name:phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester
CAS No.:912542-25-7
Molecular Formula:C₄₂H₅₉NO₅Si₂
Molecular Weight:714.105
Hs Code.:

phenyl-carbamic acid 2-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-propyl]-4-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

Synonyms:phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

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Chemical Property of phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

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Technology Process of phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

There total 5 articles about phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 912542-42-8
[2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-yl]-methanol

: 103-71-9
phenyl isocyanate

: 912542-25-7
phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

Guidance literature:: With triethylamine; In dichloromethane; at 23 ℃; for 1h;
DOI:10.1021/jo061059c

Reference yield:

: 912542-41-7
6-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-3,6-dimethyl-cyclohexa-1,4-dienecarbaldehyde

: 912542-25-7
phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / DIBAL-H / CH₂Cl₂; toluene / 0.5 h / -78 °C

2: 96 percent / VO(acac)2; t-BuOOH / CH₂Cl₂; decane / 0 - 23 °C

3: 94 percent / Et₃N / CH₂Cl₂ / 1 h / 23 °C

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; diisobutylaluminium hydride; triethylamine; In decane; dichloromethane; toluene;
DOI:10.1021/jo061059c

Reference yield:

: 912542-24-6
[6-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-3,6-dimethyl-cyclohexa-1,4-dienyl]-methanol

: 912542-25-7
phenyl-carbamic acid 2-[3-(tert-butyl-dimethyl-silanyloxy)-propyl]-4-(tert-butyl-diphenyl-silanyloxymethyl)-2,5-dimethyl-7-oxa-bicyclo[4.1.0]hept-3-en-1-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 96 percent / VO(acac)2; t-BuOOH / CH₂Cl₂; decane / 0 - 23 °C

2: 94 percent / Et₃N / CH₂Cl₂ / 1 h / 23 °C

With tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; triethylamine; In decane; dichloromethane;
DOI:10.1021/jo061059c