(-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃

Base Information

Chemical Name:(-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃
CAS No.:110043-17-9
Molecular Formula:C₃₀H₂₇NO₄PReS
Molecular Weight:714.795
Hs Code.:

(-)-(S)-(C<sub>5</sub>H<sub>5</sub>)Re(NO)PpO<sub>3</sub>SC<sub>6</sub>H<sub>4</sub>CH<sub>3</sub>

Synonyms:(-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃

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Chemical Property of (-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃

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Technology Process of (-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃

There total 1 articles about (-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: (R)-(η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 6192-52-5
p-toluenesulfonic acid monohydrate

: 110043-17-9
(-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃

Guidance literature:: In dichloromethane; acetone; soln. of Re-complex in CH2Cl2 was cooled to -24°C, soln. of 1 equiv of p-CH3C6H4SO3H*H2O in acetone was added dropwise, stirred for 30 min at 0°C; solvent removed under vac., extd. with benzene, filtered, ether added slowly to filtrate, ppt. collected, washed with ether, air dried;

Reference yield: 82.0%

: 110043-17-9
(-)-(S)-(C₅H₅)Re(NO)PpO₃SC₆H₄CH₃

: 1017-60-3
di-p-tolylphosphine

: 113036-42-3
(-)-(S)-(C₅H₅)Re(NO)PpP(C₆H₄CH₃)2H⁽¹⁺⁾*O₃sC₆H₄CH₃^(1-)

Guidance literature:: In dichloromethane; (-)-(S)-(C5H5)Re(NO)PpO3SC6H4CH3 and P(C6H4CH3)2H stirred in CH2Cl2 for 16 h; yellow oil obtained after addn. of ether; oil washed with ether and dried in vacuo;
DOI:10.1021/ja00216a015