C₅₄H₇₀N₆O₁₀S

Base Information

• Chemical Name: C₅₄H₇₀N₆O₁₀S
• CAS No.: 313352-18-0
• Molecular Formula: C₅₄H₇₀N₆O₁₀S
• Molecular Weight: 995.25
• Mol file: 313352-18-0.mol

Synonyms:C₅₄H₇₀N₆O₁₀S

Chemical Property of C₅₄H₇₀N₆O₁₀S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₄H₇₀N₆O₁₀S

There total 6 articles about C₅₄H₇₀N₆O₁₀S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

3a,6a-Bis-(4-heptyl-phenyl)-tetrahydro-imidazo[4,5-d]imidazole-2,5-dione (205862-09-5) + 6,7-bis-bromomethyl-4,9-dimethoxy-2,2-dioxo-2λ6-thia-1,3-diaza-cyclopenta[b]naphthalene-1,3-dicarboxylic acid di-tert-butyl ester (313352-17-9) → C54H70N6O10S (313352-18-0)

Guidance literature:

3a,6a-Bis-(4-heptyl-phenyl)-tetrahydro-imidazo[4,5-d]imidazole-2,5-dione; With potassium hydroxide; In tetrahydrofuran; dimethyl sulfoxide; at 85 ℃; for 0.333333h;

6,7-bis-bromomethyl-4,9-dimethoxy-2,2-dioxo-2λ⁶-thia-1,3-diaza-cyclopenta[b]naphthalene-1,3-dicarboxylic acid di-tert-butyl ester; In tetrahydrofuran; dimethyl sulfoxide; at 20 ℃; for 2h; Further stages.;

DOI:10.1021/ja002340q

Reference yield:

5,6-bis-bromomethyl-4,7-dimethoxy-2,2-dioxo-2λ6-benzo[1,2,5]thiadiazole-1,3-dicarboxylic acid di-tert-butyl ester (271800-34-1) → C54H70N6O10S (313352-18-0)

Guidance literature:

Multi-step reaction with 6 steps

1.1: 85 percent / Rongalite; TBAB / dimethylformamide / 0 - 20 °C

2.1: benzene / 2 h / Heating

3.1: DDQ / benzene / 2 h / Heating

4.1: 50 percent / DIBAL / CH₂Cl₂; toluene / 0.04 h / 0 °C

5.1: 75 percent / CBr₄; Ph₃P / tetrahydrofuran / 18 h / 20 °C

6.1: KOH / tetrahydrofuran; dimethylsulfoxide / 0.33 h / 85 °C

6.2: 22 percent / tetrahydrofuran; dimethylsulfoxide / 2 h / 20 °C

With potassium hydroxide; carbon tetrabromide; tetrabutylammomium bromide; rongalite; diisobutylaluminium hydride; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; benzene; 2.1: Diels-Alder reaction;

DOI:10.1021/ja002340q

Reference yield:

4,9-dimethoxy-2,2,7-trioxo-7,8-dihydro-5H-6-oxa-2λ6,7λ4-dithia-1,3-diaza-cyclopenta[b]naphthalene-1,3-dicarboxylic acid di-tert-butyl ester (313352-14-6) → C54H70N6O10S (313352-18-0)

Guidance literature:

Multi-step reaction with 5 steps

1.1: benzene / 2 h / Heating

2.1: DDQ / benzene / 2 h / Heating

3.1: 50 percent / DIBAL / CH₂Cl₂; toluene / 0.04 h / 0 °C

4.1: 75 percent / CBr₄; Ph₃P / tetrahydrofuran / 18 h / 20 °C

5.1: KOH / tetrahydrofuran; dimethylsulfoxide / 0.33 h / 85 °C

5.2: 22 percent / tetrahydrofuran; dimethylsulfoxide / 2 h / 20 °C

With potassium hydroxide; carbon tetrabromide; diisobutylaluminium hydride; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; toluene; benzene; 1.1: Diels-Alder reaction;

DOI:10.1021/ja002340q

upstream raw materials:

3a,6a-Bis-(4-heptyl-phenyl)-tetrahydro-imidazo[4,5-d]imidazole-2,5-dione

6,7-bis-bromomethyl-4,9-dimethoxy-2,2-dioxo-2λ⁶-thia-1,3-diaza-cyclopenta[b]naphthalene-1,3-dicarboxylic acid di-tert-butyl ester

4,9-dimethoxy-2,2,7-trioxo-7,8-dihydro-5H-6-oxa-2λ⁶,7λ⁴-dithia-1,3-diaza-cyclopenta[b]naphthalene-1,3-dicarboxylic acid di-tert-butyl ester

5,6-bis-bromomethyl-4,7-dimethoxy-2,2-dioxo-2λ⁶-benzo[1,2,5]thiadiazole-1,3-dicarboxylic acid di-tert-butyl ester