1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene

Base Information

• Chemical Name: 1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene
• CAS No.: 356775-64-9
• Molecular Formula: C₂₄H₃₆N₃O₉P₃
• Molecular Weight: 603.486
• Mol file: 356775-64-9.mol

Synonyms:1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene

Chemical Property of 1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene

There total 1 articles about 1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

1,3,5-tricyano-2,4,6-tris(bromomethyl)benzene + triethyl phosphite (122-52-1) → 1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene (356775-64-9)

Guidance literature:

In toluene; for 4h; Heating;

DOI:10.1021/ja0025595

Reference yield: 86.0%

4-(diphenylamino)benzaldehyde (4181-05-9) + 1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene (356775-64-9) → 1,3,5-tricyano-2,4,6-tris(p-diphenylaminostyryl)benzene

Guidance literature:

1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene; With lithium diisopropyl amide; In tetrahydrofuran; at 0 ℃; for 0.5h;

4-(diphenylamino)benzaldehyde; In tetrahydrofuran; at 20 ℃; for 24h; Further stages.;

DOI:10.1021/ja0025595

Reference yield: 83.0%

1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene (356775-64-9) + 4-((2-(((1,1-dimethylethyl)dimethylsilyl)oxy)ethyl)methylamino)benzaldehyde (559209-21-1) → 1,3,5-tricyano-2,4-bis{p-[N-(2-tert-butyldimethylsilanyloxyethyl)-N-methylamino]styryl}-6-(diethoxyphosphorylmethyl)benzene

Guidance literature:

1,3,5-tricyano-2,4,6-tris[(diethoxyphosphoryl)methyl]benzene; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 0.5h;

4-((2-(((1,1-dimethylethyl)dimethylsilyl)oxy)ethyl)methylamino)benzaldehyde; In tetrahydrofuran; at 20 ℃; for 24h;

DOI:10.1039/b300777d

upstream raw materials:

triethyl phosphite

Downstream raw materials:

1,3,5-tricyano-2,4-bis[(diethoxyphosphoryl)methyl]-6-(p-dihexylaminostyryl)benzene

1,3,5-tricyano-2-[(diethoxyphosphoryl)methyl]-4,6-bis(p-dihexylaminostyryl)benzene