Technology Process of C16H24
There total 3 articles about C16H24 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
5-(heptan-2-ylsulfonyl)-1-phenyl-1H-tetrazole;
With
(1,4,7,10-tetraoxacyclododecane); lithium hexamethyldisilazane;
In
tetrahydrofuran;
at -78 ℃;
for 0.0111111h;
Inert atmosphere;
3-phenyl-propionaldehyde;
In
tetrahydrofuran;
at -78 ℃;
for 0.5h;
optical yield given as %de;
Inert atmosphere;
DOI:10.1016/j.tetlet.2011.02.086
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI) / dichloromethane; toluene / 0 - 20 °C
2.1: (1,4,7,10-tetraoxacyclododecane); lithium hexamethyldisilazane / tetrahydrofuran / 0.01 h / -78 °C / Inert atmosphere
2.2: 0.5 h / -78 °C / Inert atmosphere
With
tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI); (1,4,7,10-tetraoxacyclododecane); lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; toluene;
2.1: Julia-Kocienski reaction / 2.2: Julia-Kocienski reaction;
DOI:10.1016/j.tetlet.2011.02.086
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium hydride / tetrahydrofuran; mineral oil / 0.67 h / 0 °C
1.2: 0 °C / Reflux
2.1: tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI) / dichloromethane; toluene / 0 - 20 °C
3.1: (1,4,7,10-tetraoxacyclododecane); lithium hexamethyldisilazane / tetrahydrofuran / 0.01 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 °C / Inert atmosphere
With
tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI); (1,4,7,10-tetraoxacyclododecane); sodium hydride; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; toluene; mineral oil;
3.1: Julia-Kocienski reaction / 3.2: Julia-Kocienski reaction;
DOI:10.1016/j.tetlet.2011.02.086
