(2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

Base Information

Chemical Name:(2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde
CAS No.:147122-15-4
Molecular Formula:C₂₅H₃₄O₄Si
Molecular Weight:426.628
Hs Code.:

Synonyms:(2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

There total 3 articles about (2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 88424-95-7
2,3-O-isopropylidene-1-C-<(1S)-1-methylprop-2-enyl>-D-erythro-glycerol

: 147122-15-4
(2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / imidazole / dimethylformamide / 12 h / 40 °C

2: 1) O₃/O₂, 2) PPh₃ / 1) MeOH, CH₂Cl₂, -78 deg C, 2) r.t., 2 h

With 1H-imidazole; oxygen; ozone; triphenylphosphine; In N,N-dimethyl-formamide;
DOI:10.1021/jo00060a036

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 147122-15-4
(2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / imidazole / dimethylformamide / 12 h / 40 °C

2: 1) O₃/O₂, 2) PPh₃ / 1) MeOH, CH₂Cl₂, -78 deg C, 2) r.t., 2 h

With 1H-imidazole; oxygen; ozone; triphenylphosphine; In N,N-dimethyl-formamide;
DOI:10.1021/jo00060a036

Reference yield:

: 147121-94-6
(3S,4S,5R)-4-<(tert-Butyldiphenylsilyl)oxy>-5,6-O-isopropylidene-3-methylhex-1-ene

: 147122-15-4
(2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde

Guidance literature:: With oxygen; ozone; triphenylphosphine; Yield given. Multistep reaction; 1) MeOH, CH₂Cl₂, -78 deg C, 2) r.t., 2 h;
DOI:10.1021/jo00060a036