2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Base Information

Chemical Name:2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine
CAS No.:144127-63-9
Molecular Formula:C₂₆H₃₂N₂O₄Si
Molecular Weight:464.637
Hs Code.:

Synonyms:2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Suppliers and Price of 2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

There total 7 articles about 2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 144127-94-6
10-hydroxy-2-<(2-nitrobenzyl)oxy>-7,8,9,10-tetrahydrophenanthridine

: 144127-63-9
2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ja00049a022

Reference yield: 95.0%

: 144127-63-9
2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Guidance literature:

Reference yield:

: 100713-03-9
2-hydroxy-7,8,9,10-tetrahydrophenanthridine

: 144127-63-9
2-<(2-nitrobenzyl)oxy>-10-<(triethylsilyl)oxy>-7,8,9,10-tetrahydrophenanthridine

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / potassium carbonate, tetra-n-butylammonium iodide / dimethylformamide / 3 h / 25 °C

2: 87 percent / m-CPBA / CH₂Cl₂ / 1 h / 25 °C

3: 74 percent / 1 h / 70 °C

4: 89 percent / Dowex 1*8-200 / methanol / 24 h / 60 °C

5: 95 percent / 2,6-lutidine / CH₂Cl₂ / 1 h / 20 °C

With 2,6-dimethylpyridine; Dowex 1*8-200; tetra-(n-butyl)ammonium iodide; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00049a022