16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine

Base Information

Chemical Name:16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine
CAS No.:116077-93-1
Molecular Formula:C₅₀H₅₂N₄O₆S₂
Molecular Weight:869.118
Hs Code.:

16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<b,f><1,5>diazocine

Synonyms:16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine

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Chemical Property of 16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine

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Technology Process of 16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine

There total 2 articles about 16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 109270-58-8
N,N'-(6H,12H-5,11-methanodibenzo<1,5>diazocine-2,8-diyldiethylene)bis-p-toluenesulfonamide

: 116077-92-0
bismethane

: 116077-93-1
16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 1.5h;
DOI:10.1021/ja00226a040

Reference yield:

: 620-92-8
bis-(4-hydroxyphenyl)methane

: 116077-93-1
16,36-bis(p-tolylsulfonyl)-6H,12H-2,8-(ethaniminoethanoxy<1,4>benzenomethano<1,4>benzenoxyethaniminoethano)-5,11-methanodibenzo<1,5>diazocine

Guidance literature:: Multi-step reaction with 2 steps

1: 40 percent / 40percent tetrabutylammonium hydroxide, 0.56 N NaOH / CH₂Cl₂; H₂O / 24 h / Ambient temperature

2: 43 percent / Cs₂CO₃ / dimethylformamide / 1.5 h / 80 °C

With sodium hydroxide; tetra(n-butyl)ammonium hydroxide; caesium carbonate; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/ja00226a040