ipomoeassin E

Base Information

Chemical Name:ipomoeassin E
CAS No.:850894-55-2
Molecular Formula:C₄₂H₅₈O₁₆
Molecular Weight:818.913
Hs Code.:

Synonyms:ipomoeassin E

Suppliers and Price of ipomoeassin E

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ipomoeassin E

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ipomoeassin E

There total 19 articles about ipomoeassin E which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1053260-83-5
C₄₅H₆₂O₁₆

: 850894-55-2
ipomoeassin E

Guidance literature:: With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 3h;
DOI:10.1021/ja068901g

Reference yield:

: 98-01-1
furfural

: 850894-55-2
ipomoeassin E

Guidance literature:: Multi-step reaction with 13 steps

1.1: Mg; 1,2-dibromoethane / tetrahydrofuran / 1 h / 20 °C

1.2: 82 percent / tetrahydrofuran / 2 h / 0 °C

2.1: 47 percent / Ti(OiPr)4; D-(-)-diisopropyl tartrate; t-BuOOH / CH₂Cl₂; decane / 24 h / -20 °C

3.1: 71 percent / VO(acac)2; t-BuOOH / CH₂Cl₂; decane / 3 h / 20 °C

4.1: CrO₃; H₂SO₄ / acetone / 3 h / 20 °C

5.1: 324 mg / Zn; AcOH / CHCl₃ / 3 h / 20 °C

6.1: p-TsOH*H₂O / CH₂Cl₂ / 15 h

7.1: 156 mg / triethylamine / DMAP / CH₂Cl₂ / 3 h

8.1: 68 percent / TASF / dimethylformamide / 3 h

9.1: 2,4,6-trichlorobenzoyl chloride; Et₃N / toluene / 1.5 h / 20 °C

9.2: 54.6 mg / DMAP / toluene / 2 h

10.1: RuCl₂(IMes)(PCy₃)=CHPh / CH₂Cl₂ / 4 h / Heating

11.1: 60 mg / H₂ / RhCl(PPh₃)3 / ethanol / 760 Torr

12.1: TASF; water / acetonitrile / 5 h

13.1: 14 mg / triifluoroacetic acid / CH₂Cl₂ / 3 h / 20 °C

With chromium(VI) oxide; titanium(IV) isopropylate; tert.-butylhydroperoxide; bis(acetylacetonate)oxovanadium; sulfuric acid; 2,4,6-trichlorobenzoyl chloride; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; hydrogen; D-(-)-diisopropyl tartrate; magnesium; acetic acid; ethylene dibromide; triethylamine; trifluoroacetic acid; zinc; dmap; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene](benzylidene)Ru(II) dichloride; RhCl(PPh₃)3; toluene-4-sulfonic acid; In tetrahydrofuran; decane; ethanol; dichloromethane; chloroform; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; 4.1: Jones' oxidation;
DOI:10.1021/ja068901g

Reference yield:

: 2-but-3-enyl-6-hydroxy-6H-pyran-3-one

: 850894-55-2
ipomoeassin E

Guidance literature:: Multi-step reaction with 10 steps

1.1: CrO₃; H₂SO₄ / acetone / 3 h / 20 °C

2.1: 324 mg / Zn; AcOH / CHCl₃ / 3 h / 20 °C

3.1: p-TsOH*H₂O / CH₂Cl₂ / 15 h

4.1: 156 mg / triethylamine / DMAP / CH₂Cl₂ / 3 h

5.1: 68 percent / TASF / dimethylformamide / 3 h

6.1: 2,4,6-trichlorobenzoyl chloride; Et₃N / toluene / 1.5 h / 20 °C

6.2: 54.6 mg / DMAP / toluene / 2 h

7.1: RuCl₂(IMes)(PCy₃)=CHPh / CH₂Cl₂ / 4 h / Heating

8.1: 60 mg / H₂ / RhCl(PPh₃)3 / ethanol / 760 Torr

9.1: TASF; water / acetonitrile / 5 h

10.1: 14 mg / triifluoroacetic acid / CH₂Cl₂ / 3 h / 20 °C

With chromium(VI) oxide; sulfuric acid; 2,4,6-trichlorobenzoyl chloride; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; hydrogen; acetic acid; triethylamine; trifluoroacetic acid; zinc; dmap; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene](benzylidene)Ru(II) dichloride; RhCl(PPh₃)3; toluene-4-sulfonic acid; In ethanol; dichloromethane; chloroform; N,N-dimethyl-formamide; acetone; toluene; acetonitrile; 1.1: Jones' oxidation;
DOI:10.1021/ja068901g