trans-OHC(HO)C₆H₃CH₂CHCHCH₂CH₃(OH)CHO

Base Information

• Chemical Name: trans-OHC(HO)C₆H₃CH₂CHCHCH₂CH₃(OH)CHO
• CAS No.: 1208220-59-0
• Molecular Formula: C₁₈H₁₆O₄
• Molecular Weight: 296.323
• Mol file: 1208220-59-0.mol

Synonyms:trans-OHC(HO)C₆H₃CH₂CHCHCH₂CH₃(OH)CHO

Chemical Property of trans-OHC(HO)C₆H₃CH₂CHCHCH₂CH₃(OH)CHO

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of trans-OHC(HO)C₆H₃CH₂CHCHCH₂CH₃(OH)CHO

There total 1 articles about trans-OHC(HO)C₆H₃CH₂CHCHCH₂CH₃(OH)CHO which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

3-allylsalicylaldehyde (24019-66-7) → trans-OHC(HO)C6H3CH2CHCHCH2CH3(OH)CHO (1208220-59-0) + C18H16O4

Guidance literature:

With Grubbs catalyst first generation; In dichloromethane; at 20 ℃; for 21h; optical yield given as %de; Inert atmosphere;

DOI:10.1039/b911856j

Reference yield: 96.0%

trans-OHC(HO)C6H3CH2CHCHCH2CH3(OH)CHO (1208220-59-0) → C18H18O4 (1208220-68-1)

Guidance literature:

With Wilkinson's catalyst; hydrogen; In tetrahydrofuran; at 20 ℃; for 72h; under 750.075 Torr; Inert atmosphere;

DOI:10.1039/b911856j

Reference yield: 67.0%

trans-OHC(HO)C6H3CH2CHCHCH2CH3(OH)CHO (1208220-59-0) + lutidinium p-toluene sulfonate + (1R,2R)-1,2-diaminocyclohexane (20439-47-8) + cobalt(II) diacetate tetrahydrate (6147-53-1) → [((R,R,R,R)-C48H48N4O4)Co2(p-toluene sulfonate)2]

Guidance literature:

With air; In ethanol; addn. of diamine deriv. to ethanolic soln. of benzaldehyde deriv., refluxing for 2 h, cooling, addn. of cobalt compd., refluxing for 30 min, add. of lutidinium salt at room temp., stirring at room temp. for 1 h; evapn., addn. of CH2Cl2, filtration through celite, addn. of hexane, filtration, drying in vac., NMR and MS;

DOI:10.1039/b911856j

upstream raw materials:

3-allylsalicylaldehyde

Downstream raw materials:

C₁₈H₁₈O₄