phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

Base Information

Chemical Name:phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite
CAS No.:887946-27-2
Molecular Formula:C₅₆H₅₉N₂O₁₁P
Molecular Weight:967.065
Hs Code.:

Synonyms:phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

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Chemical Property of phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

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Technology Process of phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

There total 6 articles about phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 887946-26-1
C₄₇H₄₂O₁₀

: 124482-92-4,89992-70-1
2-cyanoethyl-N,N-(diisopropylamino)chlorophosphine

: 887946-27-2
phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1021/jo0600757

Reference yield:

: 54502-85-1
phenyl 2,3-di-O-benzoyl-4,6-O-benzylidene-β-D-glucopyranoside

: 887946-27-2
phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Et₃SiH; I₂ / methanol / 12 h / 20 °C

2: 95 percent / pyridine / 12 h / 20 °C

3: 96 percent / diisopropylethylamine / CH₂Cl₂ / 0.5 h / 20 °C

With pyridine; triethylsilane; iodine; N-ethyl-N,N-diisopropylamine; In methanol; dichloromethane;
DOI:10.1021/jo0600757

Reference yield:

: 54502-82-8
(-)-(4,6-O-benzylidene)phenyl-β-D-glucopyranoside

: 887946-27-2
phenyl 6-O-(4,4'-dimethoxytriphenylmethyl)-2,3-di-O-benzoyl-β-D-glucopyranoside-4-O-(2-cyanoethyl-N,N-diisopropyl)phosphoramidite

Guidance literature:: Multi-step reaction with 4 steps

1: 3.2 g / pyridine / 12 h / 20 °C

2: 91 percent / Et₃SiH; I₂ / methanol / 12 h / 20 °C

3: 95 percent / pyridine / 12 h / 20 °C

4: 96 percent / diisopropylethylamine / CH₂Cl₂ / 0.5 h / 20 °C

With pyridine; triethylsilane; iodine; N-ethyl-N,N-diisopropylamine; In methanol; dichloromethane;
DOI:10.1021/jo0600757