Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

Base Information

Chemical Name:Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate
CAS No.:145263-11-2
Molecular Formula:C₁₂H₁₄Cl₂O₃
Molecular Weight:277.147
Hs Code.:

Synonyms:Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

Chemical Property:

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Technology Process of Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

There total 1 articles about Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 687-47-8
(S)-Ethyl lactate

: 20443-98-5
2,6-Dichlorobenzyl bromide

: 145263-11-2
Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

Guidance literature:: With silver(l) oxide; In diethyl ether; for 6h; Heating;
DOI:10.1139/v92-346

Reference yield:

: 145263-11-2
Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

: (S)-2-(2,6-Dichloro-benzyloxy)-propionaldehyde

Guidance literature:: With diisobutylaluminium hydride; In diethyl ether; hexane; at -78 ℃; for 2h;
DOI:10.1139/v92-346

Reference yield:

: 145263-11-2
Ethyl (S)-2-(2',6'-dichlorobenzyloxy)-propionate

: 102735-36-4
(2S,3S)-2-O-(2,6-dichlorobenzyl)-5-hexen-2,3-diol

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutyl aluminium hydride / diethyl ether; hexane / 2 h / -78 °C

2: zinc powder, aq. NH4Cl / H2O / 3 h / also with allylmagnesium bromide; other chiral α-alkoxy aldehydes; stereoselectivity

With diisobutylaluminium hydride; ammonium chloride; zinc; In diethyl ether; hexane; water;
DOI:10.1139/v92-346