{(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-)

Base Information

• Chemical Name: {(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-)
• CAS No.: 120120-04-9
• Molecular Formula: C₆₄H₆₄N₈NiO₄
• Molecular Weight: 1067.95
• Mol file: 120120-04-9.mol

Synonyms:{(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-)

Chemical Property of {(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-)

There total 1 articles about {(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

nickel(II) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrin (120120-01-6) → {(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-) (120120-04-9)

Guidance literature:

With potassium graphite; trifluoroacetic acid; In N,N-dimethyl-formamide; Glovebox;

DOI:10.1002/anie.202002311

Reference yield:

{(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-) (120120-04-9) → nickel(II) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrin (120120-01-6)

Guidance literature:

With methyl iodide; In tetrahydrofuran; stirring (absence of O2 and light, 1h); not isolated, detd. by NMR;

Reference yield:

{(meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrinate)Ni}(1-) (120120-04-9) → C64H64N8NiO4(2-)

Guidance literature:

Multi-step reaction with 2 steps

1: air / N,N-dimethyl-formamide

2: trifluoroacetic acid; potassium graphite / N,N-dimethyl-formamide / Glovebox

With potassium graphite; trifluoroacetic acid; In N,N-dimethyl-formamide;

DOI:10.1002/anie.202002311

upstream raw materials:

nickel(II) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrin

Downstream raw materials:

nickel(II) meso-α,α,α,α-tetrakis(o-pivalamidophenyl)porphyrin