N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

Base Information

Chemical Name:N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine
CAS No.:319914-66-4
Molecular Formula:C₂₆H₄₄N₂O₃
Molecular Weight:432.647
Hs Code.:

<i>N</i>'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-<i>N</i>,<i>N</i>-dimethyl-hydrazine

Synonyms:N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

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Chemical Property of N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

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Technology Process of N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

There total 5 articles about N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 80952-60-9
3-(Tetrahydropyran-2'-yloxy)butyliodide

: 319915-00-9
N'-(4-benzyloxymethyl-1-methyl-hexylidene)-N,N-dimethyl-hydrazine

: 319914-66-4
N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

Guidance literature:: N'-(4-benzyloxymethyl-1-methyl-hexylidene)-N,N-dimethyl-hydrazine; With lithium diisopropyl amide; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

3-(Tetrahydropyran-2'-yloxy)butyliodide; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 24h;
DOI:10.1055/s-2000-8232

Reference yield:

: 13483-31-3
Acetone dimethylhydrazone

: 319914-66-4
N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 560 mg / tetrahydrofuran; hexane / 3 h / -78 - 20 °C

2.1: LDA / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 520 mg / tetrahydrofuran; hexane / 24 h / -78 - 20 °C

With n-butyllithium; lithium diisopropyl amide; In tetrahydrofuran; hexane; 1.1: Metallation / 1.2: Alkylation / 2.1: Metallation / 2.2: Alkylation;
DOI:10.1055/s-2000-8232

Reference yield:

: 14058-59-4
2-(Benzyloxymethyl)butan-1-ol

: 319914-66-4
N'-{4-benzyloxymethyl-1-[4-(tetrahydro-pyran-2-yloxy)-pentyl]-hexylidene}-N,N-dimethyl-hydrazine

Guidance literature:: Multi-step reaction with 4 steps

1.1: 87 percent / pyridine / 0 - 20 °C

2.1: 87 percent / NaI / acetone / 2.5 h / Heating

3.1: BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: 560 mg / tetrahydrofuran; hexane / 3 h / -78 - 20 °C

4.1: LDA / tetrahydrofuran; hexane / 1 h / -78 °C

4.2: 520 mg / tetrahydrofuran; hexane / 24 h / -78 - 20 °C

With pyridine; n-butyllithium; sodium iodide; lithium diisopropyl amide; In tetrahydrofuran; hexane; acetone; 1.1: Tosylation / 2.1: Substitution / 3.1: Metallation / 3.2: Alkylation / 4.1: Metallation / 4.2: Alkylation;
DOI:10.1055/s-2000-8232