Technology Process of 1-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)-3,4-butandiol
There total 3 articles about 1-(2',3',4',6'-tetra-O-benzyl-β-D-glucopyranosyl)-3,4-butandiol which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 88 percent / diethyl ether / 2 h / -78 °C
2: 97 percent / Et3SiH, BF3*OEt2 / acetonitrile / 0.17 h / -18 °C
3: 1.) N-methylmorpholine-N-oxide, OsO4, 2.) Na2S2O3*5H2O / 1.) acetone, H2O, 3 h, 2.) acetone, H2O, ethyl acetate, 2 h
With
triethylsilane; osmium(VIII) oxide; boron trifluoride diethyl etherate; sodium thiosulfate; 4-methylmorpholine N-oxide;
In
diethyl ether; acetonitrile;
DOI:10.1016/S0040-4020(97)00273-1
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 97 percent / Et3SiH, BF3*OEt2 / acetonitrile / 0.17 h / -18 °C
2: 1.) N-methylmorpholine-N-oxide, OsO4, 2.) Na2S2O3*5H2O / 1.) acetone, H2O, 3 h, 2.) acetone, H2O, ethyl acetate, 2 h
With
triethylsilane; osmium(VIII) oxide; boron trifluoride diethyl etherate; sodium thiosulfate; 4-methylmorpholine N-oxide;
In
acetonitrile;
DOI:10.1016/S0040-4020(97)00273-1
- Guidance literature:
-
With
osmium(VIII) oxide; sodium thiosulfate; 4-methylmorpholine N-oxide;
Yield given. Multistep reaction;
1.) acetone, H2O, 3 h, 2.) acetone, H2O, ethyl acetate, 2 h;
DOI:10.1016/S0040-4020(97)00273-1
