phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate

Base Information

• Chemical Name: phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate
• CAS No.: 152329-79-8
• Molecular Formula: C₁₃H₁₁ClO₅
• Molecular Weight: 282.68
• Mol file: 152329-79-8.mol

Synonyms:phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate

Chemical Property of phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate

Chemical Property:

Purity/Quality:

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Technology Process of phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate

There total 1 articles about phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

1-phenoxy-1-trimethylsilyloxyethene (111061-31-5) + 3-chloro-4-methoxycyclobut-3-ene-1,2-dione (147899-15-8) → phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate (152329-79-8)

Guidance literature:

With titanium tetrachloride; at -15 ℃;

DOI:10.1016/S0040-4039(00)74094-9

Reference yield: 61.0%

phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate (152329-79-8) → (Z)-4-methoxy-5-<(phenoxycarbonyl)methylene>-2(5H)-furanone

Guidance literature:

With pyridine; In xylene; for 2h; Heating;

DOI:10.1016/S0040-4020(01)85262-5

Reference yield: 48.0%

phenyl (3-chloro-1-hydroxy-2-methoxy-4-oxo-2-cyclobutenyl)acetate (152329-79-8) → (4-Chloro-3-methoxy-5-oxo-2,5-dihydro-furan-2-yl)-acetic acid phenyl ester

Guidance literature:

In tetrahydrofuran; for 5h; Irradiation;

DOI:10.1016/S0040-4020(01)85262-5

upstream raw materials:

1-phenoxy-1-trimethylsilyloxyethene

3-chloro-4-methoxycyclobut-3-ene-1,2-dione